Ligand electronic effects on rates of copper mediated atom transfer radical cyclisation and polymerisation

被引：33

作者：

Clark, AJ ^{[1
]}

Battle, GM

Heming, AM

Haddleton, DM

Bridge, A

机构：

[1] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England

[2] Aventis Pharma Ltd, Dagenham RM10 7XS, Essex, England

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 10期

关键词：

radicals and radical reactions; cyclisations; copper and compounds; polymers;

D O I：

10.1016/S0040-4039(01)00061-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The effect of different N-pentyl-2-pyridylmethanimine derivatives 2a-f upon the rate of copper(I) mediated atom transfer radical cyclisation (ATRC) of 5 and living atom transfer radical polymerisation (ATRP) of methylmethacrylate were investigated. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：2003 / 2005

页数：3

共 25 条

[21] Copper(I)-catalyzed atom transfer radical polymerization [J].

Patten, TE ;

Matyjaszewski, K .

ACCOUNTS OF CHEMICAL RESEARCH, 1999, 32 (10) :895-903

[22] TRANSITION-METAL-CATALYZED, CHLORINE-TRANSFER RADICAL CYCLIZATIONS OF 2-(3-ALKEN-1-OXY)-2-CHLOROACETATES - FORMAL TOTAL SYNTHESIS OF AVENACIOLIDE AND ISOAVENACIOLIDE [J].

UDDING, JH ;

TUIJP, KCJM ;

VANZANDEN, MNA ;

HIEMSTRA, H ;

SPECKAMP, WN .

JOURNAL OF ORGANIC CHEMISTRY, 1994, 59 (08) :1993-2003

[23] CONTROLLED LIVING RADICAL POLYMERIZATION - ATOM-TRANSFER RADICAL POLYMERIZATION IN THE PRESENCE OF TRANSITION-METAL COMPLEXES [J].

WANG, JS ;

MATYJASZEWSKI, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (20) :5614-5615

[24] Controlled/"living" radical polymerization. Atom transfer radical polymerization of acrylates at ambient temperature [J].

Xia, JH ;

Gaynor, SG ;

Matyjaszewski, K .

MACROMOLECULES, 1998, 31 (17) :5958-5959

[25] Controlled/"living" radical polymerization. Atom transfer radical polymerization using multidentate amine ligands [J].

Xia, JH ;

Matyjaszewski, K .

MACROMOLECULES, 1997, 30 (25) :7697-7700

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