Significant photoelectric conversion properties of multilayer films formed by a cationic zinc phthalocyanine complex and graphene oxide

被引:7
作者
Zhang, Wei [1 ]
Li, Guoqin [1 ]
Fei, Xiaoying [1 ]
Zhang, Yu [1 ]
Tong, Jian [1 ]
Song, Xi-Ming [1 ]
机构
[1] Liaoning Univ, Coll Chem, Liaoning Key Lab Green Synth & Preparat Chem Adv, Shenyang 110036, Peoples R China
关键词
SELF-ASSEMBLED FILM; LANGMUIR-BLODGETT-FILMS; PHOTOCURRENT GENERATION; TITANIA NANOSHEETS; GRAPHITE OXIDE; HYBRID FILMS; LBL FILMS; WATER; NANOPARTICLES; AGGREGATION;
D O I
10.1039/c6ra15856k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel kind of multilayer films consisting of graphene oxide and a cationic zinc phthalocyanine complex (ImZnPc) were fabricated through an electrostatic layer-by-layer self-assembly technique and were characterized using UV-vis absorption spectroscopy, X-ray photoelectron spectroscopy and scanning electron microscopy. These multilayer films were not only homogeneously formed, but also the complex ImZnPc was absorbed on the surface of GO as a non-aggregative monomolecular film. Under visible light irradiation, these films exhibited significant cathodic photocurrent generation with good stability and reproducibility. Especially, the four-layer film exhibited a very large cathodic photocurrent density of 5.6 mu A cm(-2), which makes this novel hybrid thin film a potential material for photoelectric conversion.
引用
收藏
页码:67017 / 67024
页数:8
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