Oxygen Reduction Reaction Activity and Stability of Electrochemically Deposited Bilirubin Oxidase

被引：2
|
作者：
Takimoto, Daisuke [1 ,2 ]
Tsujimura, Seiya [1 ]
机构：
[1] Univ Tsukuba, Fac Pure & Appl Sci, Div Mat Sci, 1-1-1 Tennodai, Tsukuba, Ibaraki 3058573, Japan
[2] Shinshu Univ, Ctr Energy & Environm Sci, 3-15-1 Tokida, Ueda, Nagano 3868567, Japan
来源：
CHEMISTRY LETTERS | 2018年 / 47卷 / 10期
基金：
日本学术振兴会;
关键词：
Electrochemical deposition; Bilirubin oxidase; Stability; DIRECT ELECTRON-TRANSFER; TRANSFER-TYPE BIOELECTROCATALYSIS; CARBON ELECTRODES; O-2; REDUCTION; FUEL-CELLS; DIOXYGEN; ENZYME;
D O I：
10.1246/cl.180597
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A technique for immobilizing enzyme on Au electrode was developed. The oxygen reduction reaction activity of electrochemically deposited enzymes was higher than that of physically adsorbed enzymes. Based on the electrochemical quartz crystal microbalance measurements, the higher ORR activity of electrochemically deposited enzymes could be attributed to the proper orientation of the enzymes. In addition, the electrochemically deposited enzymes exhibited high stability with respect to potential cycles.
引用
收藏
页码：1269 / 1271
页数：3
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