Unified derivation of bohmian methods and the incorporation of interference effects

被引:38
作者
Goldfarb, Yair [1 ]
Schiff, Jeremy
Tannor, David J.
机构
[1] Weizmann Inst Sci, Dept Math, IL-76100 Rehovot, Israel
[2] Bar Ilan Univ, Dept Math, IL-52900 Ramat Gan, Israel
[3] Bar Ilan Univ, Dept Phys Chem, IL-52900 Ramat Gan, Israel
关键词
D O I
10.1021/jp0732864
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We present a unified derivation of Bohmian methods that serves as a common starting point for the derivative propagation method (DPM), Bohmian mechanics with complex action (BOMCA), and the zero-velocity complex action method (ZEVCA). The unified derivation begins with the ansatz psi = e(iS/h) where the action (S) is taken to be complex, and the quantum force is obtained by writing a hierarchy of equations of motion for the phase partial derivatives. We demonstrate how different choices of the trajectory velocity field yield different formulations such as DPM, BOMCA, and ZEVCA. The new derivation is used for two purposes. First, it serves as a common basis for comparing the role of the quantum force in the DPM and BOMCA formulations. Second, we use the new derivation to show that superposing the contributions of real, crossing trajectories yields a nodal pattern essentially identical to that of the exact quantum wavefunction. The latter result suggests a promising new approach to deal with the challenging problem of nodes in Bohmian mechanics.
引用
收藏
页码:10416 / 10421
页数:6
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