Synthesis of Phenyl Dithiocarbamates Starting from Sodium Dialkyldithiocarbamates and Aryl Boronic Acids: a Copper Catalyzed S-Arylation

被引：36

作者：

Gao, Ming-Yuan ^{[1
]}

Xu, Wan ^{[1
]}

Zhang, Shi-Bo ^{[1
]}

Li, Yue-Sheng ^{[3
]}

Dong, Zhi-Bing ^{[1
,2
]}

机构：

[1] Wuhan Inst Technol, Sch Chem & Environm Engn, Wuhan 430205, Hubei, Peoples R China

[2] Ludwig Maximilians Univ Munchen, Dept Chem, Butenandtstr 5-13, D-81377 Munich, Germany

[3] Hubei Univ Sci & Technol, Nonpower Nucl Technol Collaborat Innovat Ctr, Xianning 437100, Peoples R China

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2018年 / 2018卷 / 47期

基金：

中国国家自然科学基金;

关键词：

Dialkyldithiocarbamates; Boronic acid; Arylation; C-S coupling; Copper; ANTIFUNGAL ACTIVITY; EFFICIENT SYNTHESIS; FACILE SYNTHESIS; DERIVATIVES; ZINC; 2-AMINOBENZOTHIAZOLES; ISOTHIOCYANATES; CHEMISTRY; IODIDES; IODINE;

D O I：

10.1002/ejoc.201801271

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A convenient and efficient protocol for the S-arylation of sodium dialkyldithiocarbamates was developed. With the catalysis of copper(I) bromide, sodium dialkyldithiocarbamates coupled with aryl boronic acids giving the C-S coupling products smoothly in good to excellent yields. This protocol features easily available starting materials, easy performance, short reaction time, broad substrate scope and good yields, showing its potential synthetic value for the convenient preparation of some potentially biologically active compounds.

引用

页码：6693 / 6698

页数：6

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