Hydrophobic Modification of Ti-Containing Zeolite (TS-1) and Their Applications in Liquid-Phase Selective Catalytic Reactions

被引：14
|
作者：
Sonoda, Joji [1 ]
Kamegawa, Takashi [1 ]
Kuwahara, Yasutaka [1 ]
Mori, Kohsuke [1 ]
Yamashita, Hiromi [1 ]
机构：
[1] Osaka Univ, Div Mat & Mfg Sci, Grad Sch Engn, Suita, Osaka 5650871, Japan
来源：
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2010年 / 83卷 / 05期
关键词：
MESOPOROUS SILICA; SINGLE-SITE; PHOTOCATALYTIC REACTIVITIES; TITANIUM SILICALITES; MOLECULAR-SIEVES; LOCAL STRUCTURES; BETA ZEOLITE; OXIDE; OXIDATION; PHOTOLUMINESCENCE;
D O I：
10.1246/bcsj.20090265
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Hydrophobic modification of Ti-containing zeolite (TS-1) was performed by using triethoxyfluorosilane (TEFS). TS-1 after modification with TEFS (w = 1%) showed higher catalytic activity for the ammoximation of cyclohexanone than those on unmodified and modified TS-1 with TEFS (w = 5%) due to effective modification without covering the underlying catalytically active Ti-oxide species.
引用
收藏
页码：592 / 594
页数：3
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