Hydrothermal Syntheses and Crystal Structures of Two Layered Nickel(II) Coordination Polymers Based on 1,2,3-Benzenetricarboxylic Acid

被引：4

作者：

Wang Jing ^{[1
]}

Xu Min ^{[1
]}

Song Lingying ^{[1
]}

Liu Zhaoqing ^{[1
]}

机构：

[1] Guangzhou Univ, Sch Chem & Chem Engn, Guangzhou 510006, Guangdong, Peoples R China

来源：

CHINESE JOURNAL OF CHEMISTRY | 2011年 / 29卷 / 08期

基金：

中国国家自然科学基金;

关键词：

crystal engineering; 1,2,3-benzenetricarboxylate; coordination modes; hydrothermal synthesis; decarboxylation; METAL-ORGANIC FRAMEWORKS; PHOTOLUMINESCENT PROPERTIES; BUILDING-BLOCKS; CHEMISTRY; NETWORKS; LIGAND; CHAIN; CYCLOHEXANEHEXACARBOXYLATE; FLUORESCENCE; FLEXIBILITY;

D O I：

10.1002/cjoc.201180288

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The hydrothermal reactions of Ni(II), 1,2,3-benzenetricarboxylic acid (1,2,3-H(3)btc) and 4,4'-bipyridine (4,4'-bpy)/1,2-bis(4-pyridyl)ethane (bpa) yield two layered nickel(II) coordination polymers, [Ni(2)(1,2,3-btc)(OAc)(4,4'-bpy)(2)(H(2)O)]center dot 2H(2)O (1) and [Ni(ip)(bpa)] (2) (ip= isophthalate), respectively. Both complexes are 2-D coordination network based on 1-D Ni-carboxylate chains. The 1,2,3-btc ligand adopts 3-bridging mode in complex 1, but transformed to isophthalate (ip) ligand through decarboxylation in 2. The formation of the two complexes indicates that hydrothermal conditions and in-situ ligand reaction have significant effect on constructing coordination polymers.

引用

页码：1606 / 1612

页数：7

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