Stabilising small clusters:: synthesis and characterisation of thermolabile [Gd4F7(15-crown-5)4][AsF6]5•6SO2

被引：13

作者：

Deacon, GB

Evans, DJ

Junk, PC

Lork, E

Mews, R

Zemva, B

机构：

[1] Univ Bremen, Inst Anorgan & Phys Chem, D-28334 Bremen, Germany

[2] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia

[3] Jozef Stefan Inst, Dept Inorgan Chem, SI-1000 Ljubljana, Slovenia

来源：

DALTON TRANSACTIONS | 2005年 / 13期

关键词：

D O I：

10.1039/b504819b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Addition of 15-crown-5 to [GdF(AsF6)(2)], both dissolved in liquid SO2, and crystallisation at -30 degrees C has led to the isolation of the tetranuclear ionic complex [Gd4F7(15-crown-5)(4)][ AsF6](5)center dot 6SO(2) which is stable up to -10 degrees C where SO2 loss leads to loss of crystallinity.

引用

页码：2237 / 2238

页数：2

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