The Water Oxidation Bottleneck in Artificial Photosynthesis: How Can We Get Through It? An Alternative Route Involving a Two-Electron Process

被引：189

作者：

Inoue, Haruo ^{[1
,3
]}

Shimada, Tetsuya ^{[2
]}

Kou, Youki ^{[2
]}

Nabetani, Yu ^{[3
]}

Masui, Dai ^{[2
]}

Takagi, Shinsuke ^{[2
]}

Tachibana, Hiroshi ^{[2
]}

机构：

[1] Tokyo Metropolitan Univ, SORST JST, Tokyo 1920397, Japan

[2] Grad Sch Urban Environm Sci, Dept Appl Chem, Tokyo 1920397, Japan

[3] Ctr Prior Areas, Div Chem Convers Light Energy, Tokyo 1920397, Japan

来源：

CHEMSUSCHEM | 2011年 / 4卷 / 02期

关键词：

catalysis; oxidations; photochemistry; photosynthesis; water splitting; LIGHT-HARVESTING COMPLEX; PHOTOCHEMICAL OXYGENATION; ELECTRONIC EXCITATION; RUTHENIUM COMPLEX; CRYSTAL-STRUCTURE; DIMER COMPLEX; EVOLUTION; EFFICIENT; HYDROGEN; ARCHITECTURE;

D O I：

10.1002/cssc.201000385

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The state-of-the-art of research on artificial photosynthesis is briefly reviewed. Insights into how Nature takes electrons from water, the photon-flux density of sunlight, the time scale for the arrival of the next photon (electron-hole) at the oxygen-evolving complex, how Nature solves the photon-flux-density problem, and how we can get through the bottleneck of water oxidation are discussed. An alternate route for a two-electron process induced by one-photon excitation is postulated for getting through the bottleneck of water oxidation.

引用

页码：173 / 179

页数：7

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