Formation of CuO nanorods and their bundles by an electrochemical dissolution and deposition process

被引:75
|
作者
Toboonsung, Buppachat [1 ]
Singjai, Pisith [1 ,2 ]
机构
[1] Chiang Mai Univ, Dept Phys & Mat Sci, Fac Sci, Chiang Mai 50200, Thailand
[2] Chiang Mai Univ, Mat Sci Res Ctr, Fac Sci, Chiang Mai 50200, Thailand
关键词
Electrochemical dissolution and deposition; Heat treatment; Copper oxide; Nanorods; Photoluminescence; OXIDE THIN-FILMS; STRUCTURAL-PROPERTIES; ORIENTED AGGREGATION; COPPER; PHOTOLUMINESCENCE; NANOPARTICLES; OXIDATION; NANOCRYSTALLINE; NANOWIRES; GROWTH;
D O I
10.1016/j.jallcom.2010.12.180
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Copper oxide nanorods (NRs) and their bundles were deposited on glass substrates by an electrochemical dissolution and deposition process. Changes in the electrode separation, the deposition time and the voltage could be used to control the morphologies, the thickness and the ratio of bundles/NRs. The formation of the NRs and their bundles was explained by an aggregation mechanism. A transformation of the Cu phase in the as-deposited sample to a single CuO phase was effected by an annealing treatment at 500 degrees C. The increasing photoluminescence (PL) intensity of the annealed sample resulted from a grain size growth and an improvement in the crystallinity. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:4132 / 4137
页数:6
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