Synthesis and characterization of new metal-free and metallophthalocyanines containing spherical or cylindrical macrotricyclic moieties

被引：42
作者：
Bilgin, A
Ertem, B
Gök, Y
机构：
[1] Karadeniz Tech Univ, Dept Chem, TR-61080 Trabzon, Turkey
[2] Kocaeli Univ, Dept Sci Educ, Kocaeli, Turkey
来源：
POLYHEDRON | 2005年 / 24卷 / 10期
关键词：
phthalocyanine; cylindrical or spherical macrocycle; template effect; transition metal; macropolycyclization; isoindolinediimme;
D O I：
10.1016/j.poly.2005.01.025
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
New metal-free phthalocyanines (8-9) fused in peripheral positions with four tetraazadithiahexaoxa supercryptands were synthesized by tricyclotetramerization of isoindolinediimine derivatives of supercryptands (6-7). Metallophthalocyanines (10-11) were prepared by the reaction of the metal-free phthalocyanines with metal salts or cyclotetramerization of dicyano compounds (4-5) and anhydrous salts of some transition metal chlorides. The novel compounds were characterized by elemental analyses, IR, H-1 and C-13 NMR, UV-Vis and MS spectral data (c) 2005 Elsevier Ltd. All rights reserved.
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页码：1117 / 1124
页数：8
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