A metal-containing synthon for crystal engineering:: synthesis of the hydrogen bond ribbon polymer [4,4′-H2bipy][MCl4] (M = Pd, Pt)

被引:154
作者
Lewis, GR [1 ]
Orpen, AG [1 ]
机构
[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England
关键词
D O I
10.1039/a804128h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The utility of the cis-MCl2... HN+ chelated hydrogen bond as a synthon in preparation of crystalline [4,4'-H(2)bipy][MCl4] (M = Pd 1, Pt 2) is demonstrated; the structure of 2 contains anions and cations linked by hydrogen bonds to form a ribbon polymer.
引用
收藏
页码:1873 / 1874
页数:2
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