(Salicylaldiminato)Ni(II)-catalysts for hydrosilylation of olefins

被引：62

作者：

Srinivas, Venu ^{[1
]}

Nakajima, Yumiko ^{[1
]}

Ando, Wataru ^{[1
]}

Sato, Kazuhiko ^{[1
]}

Shimada, Shigeru ^{[1
]}

机构：

[1] Natl Inst Adv Ind Sci & Technol, Tsukuba, Ibaraki 3058565, Japan

来源：

CATALYSIS SCIENCE & TECHNOLOGY | 2015年 / 5卷 / 04期

关键词：

NICKEL-COMPLEXES BEARING; IRON CATALYSTS; PLATINUM(0)-CARBENE COMPLEXES; HYDROSILATION; TETRAHYDROFURANS; POLYMERIZATION; ALLYLSILANES; EFFICIENT; ETHYLENE;

D O I：

10.1039/c5cy00270b

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A series of (salicylaldiminato)methylnickel complexes efficiently catalyse hydrosilylation of various olefins. The complexes are highly active for secondary hydrosilanes and exhibit excellent selectivity for monohydrosilylation. A possible mechanism, which includes a silylnickel complex as a key active species, is proposed. This journal is © The Royal Society of Chemistry 2015.

引用

页码：2081 / 2084

页数：4

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