Production of renewable lubricants via self-condensation of methyl ketones

被引：35

作者：

Balakrishnan, Madhesan ^{[1
]}

Arab, George E. ^{[1
]}

Kunbargi, Omar B. ^{[1
]}

Gokhale, Amit A. ^{[2
]}

Grippo, Adam M. ^{[1
]}

Toste, F. Dean ^{[3
]}

Bell, Alexis T. ^{[4
]}

机构：

[1] Energy Biosci Inst, 2151 Berkeley way, Berkeley, CA 94720 USA

[2] BASF Corp, 33 Wood Ave South, Iselin, NJ 08830 USA

[3] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

[4] Univ Calif Berkeley, Dept Chem & Biomol Engn, Berkeley, CA 94720 USA

来源：

GREEN CHEMISTRY | 2016年 / 18卷 / 12期

关键词：

SYNTHETIC LUBRICANTS; CATALYSTS; ALCOHOLS; OLEFINS; FUELS;

D O I：

10.1039/c6gc00579a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Self-condensation of biomass-derived methyl ketones catalyzed by solid bases or acids produces corresponding cyclic trimers exclusively in excellent yields. Condensates containing 24-45 carbon atoms are shown to be suitable lubricant base-oils after the removal of residual unsaturation and oxygen. Properties of cycloalkanes produced from biomass are very similar to those of conventional lubricant base-oils. The process reported here offers an environmentally benign alternative to the current non-selective production of lubricant base-oils from a-olefins, and avoids the production of corrosive waste products.

引用

页码：3577 / 3581

页数：5

共 17 条

[1] Homogeneous catalytic hydrogenation of long-chain esters by an osmium pincer complex and its potential application in the direct conversion of triglycerides into fatty alcohols
Acosta-Ramirez, Alberto
Bertoli, Marcello
Gusev, Dmitry G.
Schlaf, Marcel
[J]. GREEN CHEMISTRY, 2012, 14 (04) : 1178 - 1188
[2] Integration of chemical catalysis with extractive fermentation to produce fuels
Anbarasan, Pazhamalai
Baer, Zachary C.
Sreekumar, Sanil
Gross, Elad
Binder, Joseph B.
Blanch, Harvey W.
Clark, Douglas S.
Toste, F. Dean
[J]. NATURE, 2012, 491 (7423) : 235 - 239
[3] Novel pathways for fuels and lubricants from biomass optimized using life-cycle greenhouse gas assessment
Balakrishnan, Madhesan
Sacia, Eric R.
Sreekumar, Sanil
Gunbas, Gorkem
Gokhale, Amit A.
Scown, Corinne D.
Toste, F. Dean
Bell, Alexis T.
[J]. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2015, 112 (25) : 7645 - 7649
[4] Green lubricants. Environmental benefits and impacts of lubrication
Boyde, S
[J]. GREEN CHEMISTRY, 2002, 4 (04) : 293 - 307
[5] Buckhalt R., 2014, SOC TRIBOLOGISTS LUB
[6] Butadiene production from bioethanol and acetaldehyde over tantalum oxide-supported ordered mesoporous silica catalysts
Chae, Ho-Jeong
Kim, Tae-Wan
Moon, Young-Kyun
Kim, Han-Kyu
Jeong, Kwang-Eun
Kim, Chul-Ung
Jeong, Soon-Yong
[J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2014, 150 : 596 - 604
[7] Engineering of Bacterial Methyl Ketone Synthesis for Biofuels
Goh, Ee-Been
Baidoo, Edward E. K.
Keasling, Jay D.
Beller, Harry R.
[J]. APPLIED AND ENVIRONMENTAL MICROBIOLOGY, 2012, 78 (01) : 70 - 80
[8] Heterogeneous Catalysts for the Guerbet Coupling of Alcohols
Kozlowski, Joseph T.
Davis, Robert J.
[J]. ACS CATALYSIS, 2013, 3 (07): : 1588 - 1600
[9] Regioselective ketone α-alkylation with simple olefins via dual activation
Mo, Fanyang
Dong, Guangbin
[J]. SCIENCE, 2014, 345 (6192) : 68 - 72
[10] Poly-α-olefin-based synthetic lubricants: a short review on various synthetic routes
Ray, Saptarshi
Rao, Peddy V. C.
Choudary, Nettem V.
[J]. LUBRICATION SCIENCE, 2012, 24 (01) : 23 - 44

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