Rearrangement of o-(chloromethyldimethylsilyl)phenylmethoxide: evidence for an apical position of the migrating group in a trigonal bipyramid intermediate

被引：14

作者：

Hijji, YM ^{[1
]}

Hudrlik, PF ^{[1
]}

Hudrlik, AM ^{[1
]}

机构：

[1] Howard Univ, Dept Chem, Washington, DC 20059 USA

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 11期

关键词：

D O I：

10.1039/a801377b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Chloromethylsilane 5a undergoes a rearrangement reaction to give oxasilacyclopentane 9 rather than oxasilacyclohexane 10, indicating that the methyl group migrates in preference to the aryl group.

引用

页码：1213 / 1214

页数：2

共 14 条

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