Two heterometallic coordination polymers based on Sr(II) ion and dicarboxylate ligand

被引：6
|
作者：
Chen, Yanmei [1 ]
Zou, Shuixiang [1 ]
Tang, Yumeng [1 ]
Hu, Hailiang [2 ]
机构：
[1] Huanggang Normal Univ, Coll Chem & Chem Engn, Hubei Key Lab Proc & Applicat Catalyt Mat, Huanggang 438000, Peoples R China
[2] Guizhou Minzu Univ, Sch Chinese Pharm, Sch Chem Engn, Guiyang 550025, Guizhou, Peoples R China
来源：
POLYHEDRON | 2019年 / 159卷
关键词：
Heterometallic coordination polymers; Luminescent properties; Alkaline earth metal complexes; Luminescence lifetimes; Zn/Cd complexes; METAL-ORGANIC FRAMEWORKS; M-II M; LUMINESCENT PROPERTIES; CRYSTAL-STRUCTURES; SR-II-LN(III) LN; SERIES; ZN; NI; CO; CU;
D O I：
10.1016/j.poly.2018.11.011
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new heterometallic coordination polymers(CPs) [ZnSr(pydc)(2)(H2O)(6)](n)center dot 2nH(2)O (1) and [CdSr (Pydc)(2)(H2O)(2)](n) (2) (H(2)pydc = pyridine-2,4-dicarboxylic acid) based on Sr-II ion and pyridine-2,4-dicarboxylate (H(2)pydc) have been solvothermally synthesized and characterized. Single crystal structure analysis shows that complex 1 is a pts topology based on Sr-Zn, and complex 2 is qtz topology based on Sr-Cd. Complex 2 was the first reported Sr-Cd complex being supported by pyridine-2,4-dicarboxylic acid. The solid state luminescent properties of 1 and 2 were studied. (C) 2018 Elsevier Ltd. All rights reserved.
引用
收藏
页码：18 / 23
页数：6
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