Molecular Design Strategies for Efficient Intramolecular Singlet Exciton Fission

被引：57

作者：

Krishnapriya, K. C. ^{[1
]}

Musser, Andrew J. ^{[2
]}

Patil, Satish ^{[1
]}

机构：

[1] Indian Inst Sci, Solid State & Struct Chem Unit, Bangalore 560012, Karnataka, India

[2] Univ Sheffield, Dept Phys & Astron, Sheffield S3 7RH, S Yorkshire, England

来源：

ACS ENERGY LETTERS | 2019年 / 4卷 / 01期

基金：

英国工程与自然科学研究理事会;

关键词：

EXTERNAL QUANTUM EFFICIENCY; CHARGE-TRANSFER STATES; TRIPLET EXCITONS; THIN-FILM; ENERGY-TRANSFER; SOLAR-CELLS; TETRACENE; PENTACENE; GENERATION; CHARACTER;

D O I：

10.1021/acsenergylett.8b01833

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The process of carrier multiplication via singlet fission can potentially exceed the Shockley-Queisser limit on the efficiency of single-junction photovoltaics. In the recent past, theoretical analysis provided the principal guidelines on molecular design strategies for singlet fission. In this Perspective, we focus instead on correlating experimental results for different classes of reported singlet fission materials to identify principles to aid in the design of new molecules for efficient intramolecular singlet fission. Building on an evaluation of several series of multichromophoric and polymeric singlet fission materials, we extract new suggested strategies for molecular design.

引用

收藏

页码：192 / 202

页数：21

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