Reductive desulfurization of organosulfur compounds with sodium in liquid ammonia

被引：7

作者：

Yu, ZK ^{[1
]}

Verkade, JG ^{[1
]}

机构：

[1] Iowa State Univ, Dept Chem, Ames, IA 50011 USA

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1998年 / 133卷

关键词：

desulfurization; sodium; liquid ammonia; organic sulfides;

D O I：

10.1080/10426509808032455

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Greater than 95% sulfur removal was observed when dialkyl mono or polysulfides were treated with Na in liquid ammonia. Polycyclic aromatic sulfur heterocycles were only moderately desulfurized under these conditions while phenylthio derivatives gave thiophenol as the major product and dithiophenols as the minor products.

引用

页码：79 / 82

页数：4

共 17 条

[1] DESULFURIZATION OF BENZOTHIOPHENES AND DIBENZOTHIOPHENES WITH NICKEL BORIDE
BACK, TG
YANG, KX
KROUSE, HR
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (07) : 1986 - 1990
[2] DERIVATIVES OF THIANAPHTHENE .1.
BLICKE, FF
SHEETS, DG
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1948, 70 (11) : 3768 - 3770
[3] BLICKE FF, 1949, J AM CHEM SOC, V71, P4010
[4] POLYFERROCENYLENE PERSULFIDES
BRANDT, PF
RAUCHFUSS, TB
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (05) : 1926 - 1927
[5] Prospects for stereocontrol in the reduction of aromatic compounds
Donohoe, TJ
Garg, R
Stevenson, CA
[J]. TETRAHEDRON-ASYMMETRY, 1996, 7 (02) : 317 - &
[6] Synthesis of [2-(dimethylphosphino)ethyl] bis(trifluoromethyl)phosphine, (CH3)(2)PCH2CH2P(CF3)(2)
Field, LD
Wilkinson, MP
[J]. TETRAHEDRON LETTERS, 1997, 38 (15) : 2779 - 2782
[7] THE CLEAVAGE OF HETEROCYCLES WITH RANEY NICKEL AND WITH LITHIUM
GILMAN, H
ESMAY, DL
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1953, 75 (12) : 2947 - 2949
[8] ORGANIC SULFUR CHEMISTRY .41. SULFUR SULFUR BOND-CLEAVAGE PROCESSES - SELECTIVE DESULFURIZATION OF TRISULFIDES
HARPP, DN
SMITH, RA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (22) : 6045 - 6053
[9] ORGANIC SULFUR CHEMISTRY .I. DISULFIDE-PHOSPHINE REACTION . DESULFURIZATION WITH TRIS(DIETHYLAMINO)PHOSPHINE
HARPP, DN
GLEASON, JG
SNYDER, JP
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (15) : 4181 - &
[10] HOLAND S, 1991, J ORG CHEM, V56, P4301

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