Structure and magnetic properties of the copper(II) complexes with diacyl hydrazides of salicylic acid

被引：5

作者：

Shul'gin, V. F. ^{[1
]}

Sarnit, E. A. ^{[1
]}

Konnik, O. V. ^{[1
]}

Rusanov, E. B. ^{[2
]}

Bogomyakov, A. S. ^{[3
]}

Ovcharenko, V. I. ^{[3
]}

Minin, V. V. ^{[4
]}

机构：

[1] Taurida Natl VI Vernadsky Univ, Simferopol, Ukraine

[2] Natl Acad Sci Ukraine, Inst Organ Chem, UA-02660 Kiev, Ukraine

[3] Russian Acad Sci, Inst Int Tomog Ctr, Siberian Branch, Novosibirsk, Russia

[4] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2012年 / 38卷 / 01期

关键词：

Salicylic Acid; Coordination Chemistry; Paramagnetic Center; Effective Magnetic Moment; Glutaric Acid;

D O I：

10.1134/S1070328411120074

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The structures and results of the static magnetic susceptibility investigation of the copper(II) binuclear complex with salicylic acid diacyl hydrazide (H2L), [Cu-2(L)(Py)(4)] (I), and the copper(II) trinuclear complex with diacyl dihydrazide of salicylic and glutaric acids (H6L'), [Cu-3(L')(Py)(4)] center dot 2Py (II), are described. The exchange antiferromagnetic interactions between the paramagnetic centers with the exchange interaction parameter -2J = 119 cm(-1) for dimer I and 14 cm(-1) for trinuclear complex II are detected.

引用

页码：44 / 49

页数：6

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