Structure and magnetic properties of the copper(II) complexes with diacyl hydrazides of salicylic acid

被引：5
|
作者：
Shul'gin, V. F. [1 ]
Sarnit, E. A. [1 ]
Konnik, O. V. [1 ]
Rusanov, E. B. [2 ]
Bogomyakov, A. S. [3 ]
Ovcharenko, V. I. [3 ]
Minin, V. V. [4 ]
机构：
[1] Taurida Natl VI Vernadsky Univ, Simferopol, Ukraine
[2] Natl Acad Sci Ukraine, Inst Organ Chem, UA-02660 Kiev, Ukraine
[3] Russian Acad Sci, Inst Int Tomog Ctr, Siberian Branch, Novosibirsk, Russia
[4] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2012年 / 38卷 / 01期
关键词：
Salicylic Acid; Coordination Chemistry; Paramagnetic Center; Effective Magnetic Moment; Glutaric Acid;
D O I：
10.1134/S1070328411120074
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The structures and results of the static magnetic susceptibility investigation of the copper(II) binuclear complex with salicylic acid diacyl hydrazide (H2L), [Cu-2(L)(Py)(4)] (I), and the copper(II) trinuclear complex with diacyl dihydrazide of salicylic and glutaric acids (H6L'), [Cu-3(L')(Py)(4)] center dot 2Py (II), are described. The exchange antiferromagnetic interactions between the paramagnetic centers with the exchange interaction parameter -2J = 119 cm(-1) for dimer I and 14 cm(-1) for trinuclear complex II are detected.
引用
收藏
页码：44 / 49
页数：6
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