Structure and magnetic properties of the copper(II) complexes with diacyl hydrazides of salicylic acid

被引：5
|
作者：
Shul'gin, V. F. [1 ]
Sarnit, E. A. [1 ]
Konnik, O. V. [1 ]
Rusanov, E. B. [2 ]
Bogomyakov, A. S. [3 ]
Ovcharenko, V. I. [3 ]
Minin, V. V. [4 ]
机构：
[1] Taurida Natl VI Vernadsky Univ, Simferopol, Ukraine
[2] Natl Acad Sci Ukraine, Inst Organ Chem, UA-02660 Kiev, Ukraine
[3] Russian Acad Sci, Inst Int Tomog Ctr, Siberian Branch, Novosibirsk, Russia
[4] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2012年 / 38卷 / 01期
关键词：
Salicylic Acid; Coordination Chemistry; Paramagnetic Center; Effective Magnetic Moment; Glutaric Acid;
D O I：
10.1134/S1070328411120074
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The structures and results of the static magnetic susceptibility investigation of the copper(II) binuclear complex with salicylic acid diacyl hydrazide (H2L), [Cu-2(L)(Py)(4)] (I), and the copper(II) trinuclear complex with diacyl dihydrazide of salicylic and glutaric acids (H6L'), [Cu-3(L')(Py)(4)] center dot 2Py (II), are described. The exchange antiferromagnetic interactions between the paramagnetic centers with the exchange interaction parameter -2J = 119 cm(-1) for dimer I and 14 cm(-1) for trinuclear complex II are detected.
引用
收藏
页码：44 / 49
页数：6
相关论文
共 50 条
  • [21] Alicyclic carboxylic acid hydrazides as copper(II) extractants
    Russ. J. Appl. Chem., 8 (1139-1145):
  • [22] Structure and magnetic properties of an oxalic acid bridged dinuclear copper(II) complex
    Saha, MK
    Sen, S
    Kundu, P
    Gupta, T
    Gramlich, V
    Mitra, S
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1998, 53 (11): : 1281 - 1284
  • [23] Novel copper(I)- and copper(II)-guanazolate complexes: Structure, network topologies, photoluminescence, and magnetic properties
    Zhang, Rui-Bo
    Zhang, Jian
    Li, Zhao-Ji
    Cheng, Jian-Kai
    Qin, Ye-Yan
    Yao, Yuan-Gen
    CRYSTAL GROWTH & DESIGN, 2008, 8 (10) : 3735 - 3744
  • [24] THE REACTION OF COPPER(II) IONS WITH ISOVALERIC ACID HYDRAZIDES
    POPEL, AA
    TROITSKAYA, AD
    SHCHUKIN, VA
    LUCHKINA, SA
    ZHURNAL NEORGANICHESKOI KHIMII, 1982, 27 (01): : 123 - 127
  • [25] MAGNETIC PROPERTIES OF SOME COPPER(II) COMPLEXES OF BENZIMIDAZOLYLALKANOLS
    HAMILTON, GJ
    KOKOT, E
    AUSTRALIAN JOURNAL OF CHEMISTRY, 1973, 26 (05) : 997 - 1003
  • [26] SYNTHESIS, CHARACTERIZATION AND MICROBIOCIDAL ACTIVITY OF COBALT(II), NICKEL(II), COPPER(II) AND ZINC(II) COMPLEXES OF ARYLOXYACETIC ACID HYDRAZIDES
    MALHOTRA, R
    KUMAR, S
    DHINDSA, KS
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1993, 32 (05): : 457 - 459
  • [27] Rhenium(IV)-copper(II) heterobimetallic complexes: Synthesis, crystal structure and magnetic properties
    Bienko, Alina
    Klak, Julia
    Mrozinski, Jerzy
    Kruszynski, Rafal
    Bienko, Dariusz C.
    Boca, Roman
    POLYHEDRON, 2008, 27 (11) : 2464 - 2470
  • [28] Heterobimetallic copper(II)-tungsten(IV/V) cyanido complexes - structure and magnetic properties
    Bogdal, Weronika
    Hodorowicz, Maciej
    Jurowska, Anna
    Mikuriya, Masahiro
    Szklarzewicz, Janusz
    JOURNAL OF MOLECULAR STRUCTURE, 2024, 1296
  • [29] Synthesis, structure and magnetic properties of phosphate-bridged polynuclear copper(II) complexes
    Zhu, Hong-Lin
    Jin, Ling
    Cheng, De-Yi
    Zheng, Yue-Qing
    INORGANICA CHIMICA ACTA, 2012, 388 : 37 - 45
  • [30] Phenylmalonate-containing copper(II) complexes:: Synthesis, crystal structure and magnetic properties
    Pasán, J
    Sanchiz, J
    Ruiz-Pérez, C
    Lloret, F
    Julve, M
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2004, (20) : 4081 - 4090
12345