Structure and magnetic properties of the copper(II) complexes with diacyl hydrazides of salicylic acid

被引：5

作者：

Shul'gin, V. F. ^{[1
]}

Sarnit, E. A. ^{[1
]}

Konnik, O. V. ^{[1
]}

Rusanov, E. B. ^{[2
]}

Bogomyakov, A. S. ^{[3
]}

Ovcharenko, V. I. ^{[3
]}

Minin, V. V. ^{[4
]}

机构：

[1] Taurida Natl VI Vernadsky Univ, Simferopol, Ukraine

[2] Natl Acad Sci Ukraine, Inst Organ Chem, UA-02660 Kiev, Ukraine

[3] Russian Acad Sci, Inst Int Tomog Ctr, Siberian Branch, Novosibirsk, Russia

[4] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2012年 / 38卷 / 01期

关键词：

Salicylic Acid; Coordination Chemistry; Paramagnetic Center; Effective Magnetic Moment; Glutaric Acid;

D O I：

10.1134/S1070328411120074

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The structures and results of the static magnetic susceptibility investigation of the copper(II) binuclear complex with salicylic acid diacyl hydrazide (H2L), [Cu-2(L)(Py)(4)] (I), and the copper(II) trinuclear complex with diacyl dihydrazide of salicylic and glutaric acids (H6L'), [Cu-3(L')(Py)(4)] center dot 2Py (II), are described. The exchange antiferromagnetic interactions between the paramagnetic centers with the exchange interaction parameter -2J = 119 cm(-1) for dimer I and 14 cm(-1) for trinuclear complex II are detected.

引用

页码：44 / 49

页数：6

共 50 条

[1] Structure and magnetic properties of the copper(II) complexes with diacyl hydrazides of salicylic acid
V. F. Shul’gin
E. A. Sarnit
O. V. Konnik
E. B. Rusanov
A. S. Bogomyakov
V. I. Ovcharenko
V. V. Minin
Russian Journal of Coordination Chemistry, 2012, 38 : 44 - 49
[2] COPPER(II) COMPLEXES OF HYDRAZIDES
BONTCHEV, PR
BONEVA, M
MITEWA, M
MEHANDJIEV, D
GOLOVINSKY, E
JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1981, 43 (12): : 3163 - 3168
[3] COMPLEXES OF COPPER(II) SULFATE WITH SOME CYCLOCARBOXYLIC ACID HYDRAZIDES
IKEKWERE, PO
PATEL, KS
NWABUEZE, JN
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1989, 19 (06): : 599 - 612
[4] MAGNETIC-PROPERTIES AND MOLECULAR-STRUCTURE OF COPPER(II) COMPLEXES OF PYRAZINECARBOXYLIC ACID
KLEIN, CL
MAJESTE, RJ
TREFONAS, LM
OCONNOR, CJ
INORGANIC CHEMISTRY, 1982, 21 (05) : 1891 - 1897
[5] MAGNETIC-PROPERTIES OF COPPER(II) COMPLEXES OF PHENYLBORONIC ACID
EMORI, S
MASUO, H
MUTO, Y
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1981, 54 (07) : 2215 - 2216
[6] COMPLEXATION WITH SALICYLIC-ACID COPPER(II) AND CALCIUM COMPLEXES
BRUN, F
SCHRODER, KH
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1975, 66 (01): : 9 - 20
[7] COMPLEXES OF SOME CYCLOCARBOXYLIC ACID HYDRAZIDES WITH COBALT(II), NICKEL(II) AND COPPER(II) NITRATES
NWABUEZE, JN
PATEL, KS
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1991, 21 (6-7): : 1017 - 1029
[8] MOLECULAR-COMPLEXES OF HYDRAZIDES WITH COPPER(II)
CARDILLO, B
GIORGINI, E
MAURELLI, E
TOSI, G
MONATSHEFTE FUR CHEMIE, 1992, 123 (03): : 231 - 236
[9] ESR AND MAGNETIC-PROPERTIES OF COPPER(II)-HYDROXYCARBOXYLIC ACID COMPLEXES
AGARWALA, BV
INORGANICA CHIMICA ACTA, 1979, 36 (02) : 209 - 212
[10] THERMAL-BEHAVIOR OF COPPER(II) COMPLEXES OF SALICYLIC-ACID
YOSHIMURA, Y
OKI, H
TSUCHIYA, R
NIPPON KAGAKU KAISHI, 1979, (04) : 506 - 510

← 1 2 3 4 5 →