A New Luminescent Cd(II) Compound for the Reversible Sensing of Nitrobenzene

被引：1

作者：

Wang, Jian-Min ^{[1
]}

机构：

[1] Xian Shiyou Univ, Coll Chem & Chem Engn, Xian, Peoples R China

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2015年 / 45卷 / 11期

关键词：

Cd(II); hydrothermal synthesis; luminescence sensing; open framework; COORDINATION POLYMERS; CHEMICAL SENSORS; METAL-IONS; FRAMEWORKS;

D O I：

10.1080/15533174.2013.865223

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new Cd(II) coordination polymer, namely {[(CH3)(2)NH2][Cd(BTC)(H2O)]}(n) (1, H3BTC = 1,3,5-benzenetricaboxylic acid), has been hydrothermally synthesized by combination of Cd(NO3)(2) and H3BTC. Single-crystal X-ray diffraction analysis reveals that compound 1 features a 3D anionic open framework balanced by the dimethylamine cations. Topological analysis reveals that it can be simplified into a (3,6)-connected rutile (rtl) network with the Schlafli symbol of {4.6(2)}(2){4(2).6(10).8(3)}. Moreover, compound 1 emits intense luminescence at room temperature and displays reversible sensing for nitrobenzene.

引用

页码：1739 / 1742

页数：4

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