A New Luminescent Cd(II) Compound for the Reversible Sensing of Nitrobenzene

被引：1
|
作者：
Wang, Jian-Min [1 ]
机构：
[1] Xian Shiyou Univ, Coll Chem & Chem Engn, Xian, Peoples R China
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2015年 / 45卷 / 11期
关键词：
Cd(II); hydrothermal synthesis; luminescence sensing; open framework; COORDINATION POLYMERS; CHEMICAL SENSORS; METAL-IONS; FRAMEWORKS;
D O I：
10.1080/15533174.2013.865223
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new Cd(II) coordination polymer, namely {[(CH3)(2)NH2][Cd(BTC)(H2O)]}(n) (1, H3BTC = 1,3,5-benzenetricaboxylic acid), has been hydrothermally synthesized by combination of Cd(NO3)(2) and H3BTC. Single-crystal X-ray diffraction analysis reveals that compound 1 features a 3D anionic open framework balanced by the dimethylamine cations. Topological analysis reveals that it can be simplified into a (3,6)-connected rutile (rtl) network with the Schlafli symbol of {4.6(2)}(2){4(2).6(10).8(3)}. Moreover, compound 1 emits intense luminescence at room temperature and displays reversible sensing for nitrobenzene.
引用
收藏
页码：1739 / 1742
页数：4
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