Catalytic activity of palladium doped activated carbon from waste coffee on some environmental pollutants

被引:18
作者
Karaoglu, Kaan [1 ]
Ozcifci, Zehra [2 ]
caliskan, Melike [3 ]
Baran, Talat [3 ]
Akcay, Hakki Turker [2 ]
机构
[1] Recep Tayyip Erdogan Univ, Vocat Sch Tech Sci, Dept Chem & Chem Proc Technol, Rize, Turkey
[2] Recep Tayyip Erdogan Univ, Fac Arts & Sci, Dept Chem, Rize, Turkey
[3] Aksaray Univ, Fac Arts & Sci, Dept Chem, Aksaray, Turkey
关键词
Waste coffee spent; Heterogenous catalyst; Nitroarmatics; DENSITY-FUNCTIONAL THEORY; PORE-SIZE DISTRIBUTION; GREEN SYNTHESIS; PD NANOPARTICLES; CONGO RED; RECYCLABLE CATALYST; EFFICIENT REDUCTION; FACILE PREPARATION; AG NANOPARTICLES; POROUS CARBONS;
D O I
10.1016/j.matchemphys.2022.125857
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The presence of nitro compounds and such commercial dyes as Congo red, methylene blue, methyl orange and methyl red in water/wastewater causes environmental issues. The treatment of such industrial contaminants, new efficient hybrid catalysts are designed by Research groups all around the world. For this aim, a large of catalyst systems were designed and their water treatment capacities were investigated. As a part of Green Chemistry approach, food wastes could be used for production of porous carbon materials. In this work, a palladium/activated carbon hybrid catalyst (AC-Pd) was prepared and characterized by XRD, SEM/EDS and TEM. It was found from TEM analysis that the average particle size of AC-Pd hybrid was about 54 nm. The reduction capacity of AC-Pd for nitroarenes and organic dyes was investigated by UV-Vis. spectroscopy in aqueous media. According to catalytic tests results, AC-Pd nanocatalyst could be used in reduction of both nitro compounds and organic dyes.
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页数:7
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