Catalytic activity of palladium doped activated carbon from waste coffee on some environmental pollutants

被引:18
作者
Karaoglu, Kaan [1 ]
Ozcifci, Zehra [2 ]
caliskan, Melike [3 ]
Baran, Talat [3 ]
Akcay, Hakki Turker [2 ]
机构
[1] Recep Tayyip Erdogan Univ, Vocat Sch Tech Sci, Dept Chem & Chem Proc Technol, Rize, Turkey
[2] Recep Tayyip Erdogan Univ, Fac Arts & Sci, Dept Chem, Rize, Turkey
[3] Aksaray Univ, Fac Arts & Sci, Dept Chem, Aksaray, Turkey
关键词
Waste coffee spent; Heterogenous catalyst; Nitroarmatics; DENSITY-FUNCTIONAL THEORY; PORE-SIZE DISTRIBUTION; GREEN SYNTHESIS; PD NANOPARTICLES; CONGO RED; RECYCLABLE CATALYST; EFFICIENT REDUCTION; FACILE PREPARATION; AG NANOPARTICLES; POROUS CARBONS;
D O I
10.1016/j.matchemphys.2022.125857
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The presence of nitro compounds and such commercial dyes as Congo red, methylene blue, methyl orange and methyl red in water/wastewater causes environmental issues. The treatment of such industrial contaminants, new efficient hybrid catalysts are designed by Research groups all around the world. For this aim, a large of catalyst systems were designed and their water treatment capacities were investigated. As a part of Green Chemistry approach, food wastes could be used for production of porous carbon materials. In this work, a palladium/activated carbon hybrid catalyst (AC-Pd) was prepared and characterized by XRD, SEM/EDS and TEM. It was found from TEM analysis that the average particle size of AC-Pd hybrid was about 54 nm. The reduction capacity of AC-Pd for nitroarenes and organic dyes was investigated by UV-Vis. spectroscopy in aqueous media. According to catalytic tests results, AC-Pd nanocatalyst could be used in reduction of both nitro compounds and organic dyes.
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页数:7
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共 66 条
  • [1] Preparation of amine functionalized g-C3N4@H/SMOF NCs with visible light photocatalytic characteristic for 4-nitrophenol degradation from aqueous solution
    Abazari, Reza
    Mahjoub, Ali Reza
    Salehi, Ghazal
    [J]. JOURNAL OF HAZARDOUS MATERIALS, 2019, 365 : 921 - 931
  • [2] Coffee-derived activated carbon from second biowaste for supercapacitor applications
    Adan-Mas, Alberto
    Alcaraz, Lorena
    Arevalo-Cid, Pablo
    Lopez-Gomez, Felix. A.
    Montemor, Fatima
    [J]. WASTE MANAGEMENT, 2021, 120 (120) : 280 - 289
  • [3] Activated carbon derived from tea waste: A promising supporting material for metal nanoparticles used as catalysts in hydrolysis of ammonia borane
    Akbayrak, Serdar
    Ozcifci, Zehra
    Tabak, Ahmet
    [J]. BIOMASS & BIOENERGY, 2020, 138 (138)
  • [4] Pd nanoparticles for C-C coupling reactions
    Balanta, Angelica
    Godard, Cyril
    Claver, Carmen
    [J]. CHEMICAL SOCIETY REVIEWS, 2011, 40 (10) : 4973 - 4985
  • [5] Generation and characterization of palladium nanocatalyst anchored on a novel polyazomethine support: Application in highly efficient and quick catalytic reduction of environmental contaminant nitroarenes
    Baran, Nuray Yilmaz
    [J]. JOURNAL OF MOLECULAR STRUCTURE, 2020, 1220
  • [6] Pd/CoFe2O4/chitosan: A highly effective and easily recoverable hybrid nanocatalyst for synthesis of benzonitriles and reduction of 2-nitroaniline
    Baran, Talat
    Nasrollahzadeh, Mahmoud
    [J]. JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2021, 149
  • [7] Electrochemical nitrate reduction of brines: Improving selectivity to N2 by the use of Pd/activated carbon fiber catalyst
    Beltrame, Thiago Favarini
    Zoppas, Fernanda Miranda
    Gomes, Maria Carolina
    Ferreira, Jane Zoppas
    Marchesini, Fernanda Albana
    Bernardes, Andrea Moura
    [J]. CHEMOSPHERE, 2021, 279
  • [8] Environmental occurrence, toxicity concerns, and remediation of recalcitrant nitroaromatic compounds
    Bilal, Muhammad
    Bagheri, Ahmad Reza
    Bhatt, Pankaj
    Chen, Shaohua
    [J]. JOURNAL OF ENVIRONMENTAL MANAGEMENT, 2021, 291
  • [9] Dehydration of glucose to 5-Hydroxymethlyfurfural on bifunctional carbon catalysts
    Bounoukta, Charf Eddine
    Megias-Sayago, Cristina
    Ammari, Fatima
    Ivanova, Svetlana
    Monzon, Antonio
    Centeno, Miguel Angel
    Odriozola, Jose Antonio
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2021, 286
  • [10] Adsorption of gases in multimolecular layers
    Brunauer, S
    Emmett, PH
    Teller, E
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1938, 60 : 309 - 319