Fabrication of a High-Quality Cu2ZnSn(S,Se)4 Absorber Layer via an Aqueous Solution Process and Application in Solar Cells

被引：8
|
作者：
Zhao, Wangen [1 ,2 ,3 ]
Yu, Fengyang [1 ,2 ,3 ]
Liu, Shengzhong Frank [1 ,2 ,3 ,4 ,5 ]
机构：
[1] Shaanxi Normal Univ, Minist Educ, Key Lab Appl Surface & Colloid Chem, Xian 710062, Shaanxi, Peoples R China
[2] Shaanxi Normal Univ, Shaanxi Engn Lab Adv Energy Technol, Xian 710062, Shaanxi, Peoples R China
[3] Shaanxi Normal Univ, Sch Mat Sci & Engn, Xian 710062, Shaanxi, Peoples R China
[4] Chinese Acad Sci, IChEM Collaborat Innovat Ctr Chem Energy Mat, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
[5] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
来源：
ACS APPLIED MATERIALS & INTERFACES | 2019年 / 11卷 / 01期
基金：
中国国家自然科学基金;
关键词：
CZTSSe; CZTSe; aqueous solution process; selenization treatment; thin-film solar cells; HIGH-EFFICIENCY; THIN-FILM; CU2ZNSNS4; PRECURSORS; SEMICONDUCTORS; CONVERSION; DEFECTS; TERNARY; BINARY;
D O I：
10.1021/acsami.8b15354
中图分类号：
TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
The development of Cu2ZnSn(S,Se)(4) (CZTSSe) solar cells determines the prospect of thin-film photovoltaic devices because of some of their strengths. However, the usual solution fabrication processes of CZTSSe absorbing layers are either too tedious or highly toxic. Here, we have developed an alternative strategy to prepare kesterite CZTSSe absorber films with a simple and low-toxicity solution process by replacing the commonly employed thiol-based compounds using the glycolic acid aqueous solution, which significantly reduces the environment pollution and toxicity, providing a possibility toward the green solvent process. The power conversion efficiency of 6.81% has been acquired based the aqueous solution-processed CZTSSe thin film via optimizing the fabrication technology.
引用
收藏
页码：634 / 639
页数：6
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