An easy access to aryl azides from aryl amines under neutral conditions

被引：55
作者：
Das, J [1 ]
Patil, SN [1 ]
Awasthi, R [1 ]
Narasimhulu, CP [1 ]
Trehan, S [1 ]
机构：
[1] Dr Reddys Labs Ltd, Discovery Res, Hyderabad 500049, Andhra Pradesh, India
来源：
SYNTHESIS-STUTTGART | 2005年 / 11期
关键词：
amines; azides; anilines; diazo compounds; sodium azide;
D O I：
10.1055/s-2005-869974
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A variety of substituted aryl amines were transformed into aryl azides using t-BuONO and moist NaN3 in t-BuOH in good to excellent yields. Smooth transformation was observed with anilines, having electron withdrawing and donating groups. Both acid- and base-sensitive groups survived the reaction conditions.
引用
收藏
页码：1801 / 1806
页数：6
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