A practical and efficient synthesis of chiral N,N-disubstituted C2 symmetric diamines derived from (R,R)-1,2-diaminocyclohexane

被引:30
|
作者
Alexakis, A [1 ]
Chauvin, AS [1 ]
Stouvenel, R [1 ]
Vrancken, E [1 ]
Mutti, S [1 ]
Mangeney, P [1 ]
机构
[1] Univ Geneva, Dept Organ Chem, CH-1211 Geneva 4, Switzerland
关键词
D O I
10.1016/S0957-4166(01)00198-7
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
An improved synthesis of chiral diamine ligands derived from (R,R)-1,2-diaminocyclohexane is described, providing N-substituted diamines. The synthesis of other neu ligands based on this methodology, is also reported. (C) 2001 Elsevier Science Ltd. All rights reserved.
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页码:1171 / 1178
页数:8
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