Non-innocent ligand reservoirs for reducing or oxidizing equivalents in carbonylrhenium(I) complexes: 1,1′-Bis(diphenylphosphino)ferrocene (dppf) and bis-triazinyl-pyridine (BTP)

被引：14
|
作者：
Roy, Sayak [1 ]
Blane, Travis [1 ]
Lilio, Alyssia [1 ]
Kubiak, Clifford P. [1 ]
机构：
[1] Univ Calif San Diego, Dept Chem & Biochem, La Jolla, CA 92093 USA
来源：
INORGANICA CHIMICA ACTA | 2011年 / 374卷 / 01期
关键词：
Re(I)-carbonyl complexes; Ferrocene; Electrochemistry; Spectroelectrochemistry; CARBON-DIOXIDE; METAL-COMPLEXES; REDUCTION; STATE; RUTHENIUM(II); BEHAVIOR; URANIUM; RE(I); CO2;
D O I：
10.1016/j.ica.2011.02.005
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Organometallic complexes of Re(I) with ligands having opposite redox properties have been synthesized and structurally characterized. X-ray crystal structures of the complexes show typical fac-Re-I(CO)(3) coordination to the redox active ligands. Complete electrochemical and spectroelectrochemical studies on the ligands and the metal complexes were performed. The IR-spectroelectrochemical responses were monitored using the fac-Re(CO)(3) unit as a probe. The 15-20 cm(-1) hypsochromic or bathochromic shift of the nu(CO) bands upon reduction or oxidation is attributed to ligand-centered processes. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码：134 / 139
页数：6
相关论文
共 11 条
  • [1] Heterobimetallic Cu-dppf (dppf=1,1′-Bis(diphenylphosphino)ferrocene) Complexes with "Click" Derived Ligands: A Combined Structural, Electrochemical, Spectroelectrochemical, and Theoretical Study
    Schweinfurth, David
    Buettner, Nadin
    Hohloch, Stephan
    Deibel, Naina
    Klein, Johannes
    Sarkar, Biprajit
    ORGANOMETALLICS, 2013, 32 (20) : 5834 - 5842
  • [2] Group 11 complexes with the 1,1′Bis[N,N′-(2-(diphenylphosphino) amide] ferrocene ligand
    Javier E. Aguado
    M. Concepción Gimeno
    Antonio Laguna
    M. Dolores Villacampa
    Gold Bulletin, 2009, 42 : 302 - 309
  • [3] Group 11 complexes with the 1,1′Bis[N,N′-(2-(diphenylphosphino) amide] ferrocene ligand
    Aguado, Javier E.
    Concepcion Gimeno, M.
    Laguna, Antonio
    Dolores Villacampa, M.
    GOLD BULLETIN, 2009, 42 (04) : 302 - 309
  • [4] Silver(I) complexes with the 1,1′-bis(diethyldithiocarbamate)ferrocene ligand.: Polymeric chain species
    Gimeno, MC
    Jones, PG
    Laguna, A
    Sarroca, C
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2004, 59 (11-12): : 1365 - 1371
  • [5] Heteroleptic Cu(I) complexes containing phenanthroline-type and 1,1′-bis(diphenylphosphino)ferrocene ligands:: Structure and electronic properties
    Armaroli, Nicola
    Accorsi, Gianluca.
    Bergamini, Giacomo
    Ceroni, Paola
    Holler, Michel
    Moudam, Omar
    Duhayon, Carine
    Delavaux-Nicot, Beatrice
    Nierengarten, Jean-Francois
    INORGANICA CHIMICA ACTA, 2007, 360 (03) : 1032 - 1042
  • [6] 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE COMPLEXES OF GOLD(I) - POLYMERIC [AUCL(MU-DPPF)]N AND DIMERIC [AU2(DPPF-P,P')2(MU-DPPF)](NO3)2
    PHANG, LT
    HOR, TSA
    ZHOU, ZY
    MAK, TCW
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 469 (02) : 253 - 261
  • [7] Heterobimetallic compounds [Ru(η5-Cp)(dppf)X] (X = Cl, Br, I and N3): synthesis, electrochemical analysis, and the crystal structure of [Ru(η5-Cp)(dppf)I] [dppf=1,1'-bis(diphenylphosphino)ferrocene]
    Paim, Lilian A.
    Batista, Alzir A.
    Dias, Fabricia M.
    Golfeto, Camilla C.
    Ellena, Javier
    Siebald, Helmuth G. L.
    Ardisson, J. D.
    TRANSITION METAL CHEMISTRY, 2009, 34 (08) : 949 - 954
  • [8] Heterobimetallic compounds [Ru(η5-Cp)(dppf)X] (X = Cl, Br, I and N3): synthesis, electrochemical analysis, and the crystal structure of [Ru(η5-Cp)(dppf)I] [dppf = 1,1′-bis(diphenylphosphino)ferrocene]
    Lilian A. Paim
    Alzir A. Batista
    Fabrícia M. Dias
    Camilla C. Golfeto
    Javier Ellena
    Helmuth G. L. Siebald
    J. D. Ardisson
    Transition Metal Chemistry, 2009, 34 : 949 - 954
  • [9] Cleavage of the dimeric heterometallic complexes [Pd(dppf) (?-Cl)]2[BArF24]2 (dppf=1,1?-bis(diphenylphosphino)ferrocene, BArF24 = tetrakis(bis-3,5-trifluoromethylphenyl)borate) via addition of monodentate phosphine ligands
    Wolfarth, Sadie A.
    Colicchio, Nick G.
    Nataro, Cassie S.
    Reinheimer, Eric W.
    Nataro, Chip
    POLYHEDRON, 2022, 222
  • [10] Heterotetranuclear Complexes of Reduced and Non-reduced Bridging 1,2,4,5-Tetrazine Ligands 1,1′-Bis(diphenylphosphanyl)-ferrocene-copper(I)
    Bach, Monika
    Roy, Sayak
    Sarkar, Biprajit
    Bubrin, Martina
    Niemeyer, Mark
    Fiedler, Jan
    Duboc, Carole
    Kaim, Wolfgang
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2015, 641 (02): : 327 - 331
12