Crystal and molecular structure of the potassium salt of 2,4-di-iso-propoxy-6-dinitromethyl-1,3,5-triazine

被引：1

作者：

Bakharev, V. V. ^{[1
]}

Gidaspov, A. A. ^{[1
]}

Litvinov, I. A. ^{[2
]}

Mironova, E. V. ^{[2
]}

机构：

[1] Samara State Tech Univ, Samara, Russia

[2] Kazan Sci Ctr, AE Arbuzov Organ & Phys Chem Inst, Kazan, Russia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2007年 / 48卷 / 06期

关键词：

organic chemistry; crystal structure; potassium salt of 2,4-di-iso-propoxy-6-dinitromethyl-1,3,5-triazine;

D O I：

10.1007/s10947-007-0188-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An X-ray diffraction study of the potassium salt of 2,4-di-iso-propoxy-6-dinitromethyl-1,3,5-triazine was performed. Monoclinic crystals, C10H14N5O6- center dot K+; M = 339.36; a = 9.645(2) angstrom, b = 8.803(2) angstrom, c = 17.686(3) angstrom; beta = 92.50(2)degrees; V = 1500.2(5) angstrom 3, d(c) = 1.50 g/cm(3), Z = 4, space group P2(1)/a. The 2,4-di-iso-propoxy-6-dinitromethyl-1,3,5-triazine anion is nonplanar. The 1,3,5-triazine heterocycle is planar; the angle between the ring and the dinitromethyl fragment is 87.9(5)degrees. The potassium cation is in the general position; its coordination number is 7. The cation is bonded to four 2,4-di-iso-propoxy-6-dinitromethyl-1,3,5-triazine molecules. Infinite layers are formed due to the coordination bonds in crystal.

引用

页码：1164 / 1167

页数：4

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