Rhodium-catalyzed regio- and stereoselective codimerization of alkenes and electron-deficient internal alkynes leading to 1,3-dienes

被引：47
|
作者：
Shibata, Yu [1 ]
Hirano, Masao [1 ]
Tanaka, Ken [1 ]
机构：
[1] Tokyo Univ Agr & Technol, Grad Sch Engn, Dept Appl Chem, Koganei, Tokyo 1848588, Japan
来源：
ORGANIC LETTERS | 2008年 / 10卷 / 13期
关键词：
D O I：
10.1021/ol800995r
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A cationic rhodium(I)/H(8)-BINAP complex catalyzes codimerization of alkenes bearing no alpha-hydrogen and electron-deficient internal alkynes, leading to 1,3-dienes in good yields with moderate to excellent regio- and stereoselectivity. The same complex also catalyzes codimerization of an acrylate and phenyl-substituted electron-rich internal alkynes, leading to 1,3-dienes.
引用
收藏
页码：2829 / 2831
页数：3
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