Synthesis and characterization of palladium (II) complexes

被引:0
|
作者
Mishra, A. K. [1 ]
Mishra, S. B. [2 ]
Manav, N. [1 ]
Kaushik, N. K. [1 ]
机构
[1] Univ Delhi, Dept Chem, Delhi 110007, India
[2] Univ Free State, Dept Chem, ZA-9866 Bloemfontein, South Africa
关键词
D O I
暂无
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Palladium (II) complexes of type [Pd(L)Cl-2] [where, L= benzyl-N-thiohydrazide (L-1), (benzyl-N-thio)-1,3-propanediamine (L-2), benzaldehyde benzyl-N-thiohydrazone (L-3) and salicylaldehyde-benzyl-N-thiohydrazone (L-4)] have been synthesized. The thiohydrazides, thiodiamine and thiohydrazones can exist as thione-thiol tautomer and coordinate as as a bidentate N-S ligand. The ligands were found to act in monobasic bidentate fashion. The complexes have been characterized by elemental analysis, IR, mass, electronic and H-1 NMR spectroscopic studies.
引用
收藏
页码:449 / 458
页数:10
相关论文
共 50 条
  • [21] SYNTHESIS AND CHARACTERIZATION OF SOME CATIONIC CHIRAL PALLADIUM(II) COMPLEXES
    HOLT, H
    HANKS, TW
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1993, 206 : 291 - INOR
  • [22] Synthesis, characterization and cytotoxic activity of palladium (II) carbohydrate complexes
    Deepthi, S. Bhavya
    Trivedi, Rajiv
    Sujitha, P.
    Kumar, C. Ganesh
    Sridhar, B.
    Bhargava, Suresh K.
    JOURNAL OF CHEMICAL SCIENCES, 2012, 124 (06) : 1405 - 1413
  • [23] Synthesis and characterization of palladium(II) u-terpyridine complexes
    Adrian, Rafael A.
    Zapata, Adrian L.
    Sanchez, Nicole
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2009, 238
  • [24] Synthesis and structural characterization of dinuclear tellurolate palladium(II) complexes
    Back, Davi
    de Oliveira, Gelson Manzoni
    Lang, Ernesto Schulz
    POLYHEDRON, 2015, 85 : 565 - 569
  • [25] Synthesis and characterization of chiral tetraaza macrocyclic nickel(II) and palladium(II) complexes
    Du, GD
    Ellern, A
    Woo, LK
    INORGANIC CHEMISTRY, 2003, 42 (03) : 873 - 877
  • [26] SYNTHESIS, CHARACTERIZATION, AND REACTIONS OF ALKYL PALLADIUM(II) AND PLATINUM(II) TRIFLUOROACETATE COMPLEXES
    KIM, YJ
    LEE, JY
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 1995, 16 (06) : 558 - 561
  • [27] Synthesis, characterization and electrochemistry of ferrocenylselenolate bridged palladium(II) and platinum(II) complexes
    Brown, MJ
    Corrigan, JF
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2004, 689 (18) : 2872 - 2879
  • [28] Synthesis, characterization, and structures of nickel(II) and palladium(II) complexes of aromatic thiohydrazides
    Mukherjee, S.
    Gangopadhyay, S.
    Zangrando, E.
    Gangopadhyay, P. K.
    JOURNAL OF COORDINATION CHEMISTRY, 2011, 64 (21) : 3700 - 3710
  • [29] Synthesis and spectroscopic characterization of palladium(II) and platinum(II) complexes with substituted pyrazoles
    Adhikari, Nimairatan
    Saha, Nityananda
    ASIAN JOURNAL OF CHEMISTRY, 2008, 20 (01) : 521 - 529
  • [30] Synthesis, characterization and toxicity of new heterobimetallic complexes of platinum(II) and palladium(II)
    Sharma, K
    Fahmi, N
    Singh, RV
    APPLIED ORGANOMETALLIC CHEMISTRY, 2001, 15 (03) : 221 - 226