Rhodium-catalyzed intermolecular silylcarbamoylation of acetylenic bonds

被引：9
|
作者：
Matsuda, I [1 ]
Takeuchi, K [1 ]
Itoh, K [1 ]
机构：
[1] Nagoya Univ, Grad Sch Engn, Dept Appl Chem, Nagoya, Aichi 4648603, Japan
来源：
TETRAHEDRON LETTERS | 1999年 / 40卷 / 13期
关键词：
alpha; beta-unsaturated amides; carbonylation of alkynes; hydrosilanes; rhodium catalyst;
D O I：
10.1016/S0040-4039(99)00200-2
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
alpha,beta-Unsaturated amides are readily formed by silylcarbamoylation of an acetylenic bond which is accomplished intermolecularly by a one-pot reaction of four components, an alkyne, a hydrosilane, an amine, and CO in the presence of a catalytic amount of Rh-4(CO)(12). (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：2553 / 2556
页数：4
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