Rhodium-catalyzed intermolecular silylcarbamoylation of acetylenic bonds

被引：9

作者：

Matsuda, I ^{[1
]}

Takeuchi, K ^{[1
]}

Itoh, K ^{[1
]}

机构：

[1] Nagoya Univ, Grad Sch Engn, Dept Appl Chem, Nagoya, Aichi 4648603, Japan

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 13期

关键词：

alpha; beta-unsaturated amides; carbonylation of alkynes; hydrosilanes; rhodium catalyst;

D O I：

10.1016/S0040-4039(99)00200-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

alpha,beta-Unsaturated amides are readily formed by silylcarbamoylation of an acetylenic bond which is accomplished intermolecularly by a one-pot reaction of four components, an alkyne, a hydrosilane, an amine, and CO in the presence of a catalytic amount of Rh-4(CO)(12). (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：2553 / 2556

页数：4

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