Catalytic asymmetric metal carbene transformations

被引:28
|
作者
Forbes, DC [1 ]
McMills, MC
机构
[1] Univ S Alabama, Dept Chem, Mobile, AL 36608 USA
[2] Ohio Univ, Dept Chem & Biochem, Athens, OH 45701 USA
关键词
D O I
10.2174/1385272013374815
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The application of stabilized metal carbenes as reactive intermediates in synthesis has greatly expanded because of the wide array of structures that are available from these reactions. In order to expand the usefulness of these reactions, several investigators have focused on the development of chiral catalysts that cab effect asymmetric carbene reactions. This review will cover the development and application of these catalysts.
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页码:1091 / 1105
页数:15
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