Sunlight-driven synthesis of γ-diketones via oxidative coupling of enamines with silyl enol ethers catalyzed by [Ru(bpy)3]2+

被引：70

作者：

Yasu, Yusuke ^{[1
]}

Koike, Takashi ^{[1
]}

Akita, Munetaka ^{[1
]}

机构：

[1] Tokyo Inst Technol, Chem Resources Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 43期

关键词：

VISIBLE-LIGHT PHOTOCATALYSIS; PHOTOREDOX CATALYSIS; GREEN PHOTOCHEMISTRY; FINE CHEMICALS; STRATEGY; ORGANOCATALYSIS; ALKYLATION;

D O I：

10.1039/c2cc31748f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A photosensitizer [Ru(bpy)(3)](2+) catalyzes oxidative coupling reaction of enamines with silyl enol ethers under visible light irradiation by a Xe lamp or sunlight to produce gamma-diketones. A 2e-oxidation process involved in this reaction is achieved by a combination of the photoexcited [Ru(bpy)(3)](2+) species and duroquinone, a 2e-acceptor.

引用

页码：5355 / 5357

页数：3

共 5 条

[1] Photoinduced Oxyamination of Enamines and Aldehydes with TEMPO Catalyzed by [Ru(bpy)3]2+
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CHEMISTRY LETTERS, 2009, 38 (02) : 166 - 167
[2] [Ru(bpy)3]Cl2-catalyzed aerobic oxidative cleavage β-diketones to carboxylic acids under visible light irradiation
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[3] Synthesis of Tetrasubstituted Furans by Using Photoredox-Catalyzed Coupling of 2-Bromo-1,3-dicarbonyl Compounds with Silyl Enol Ethers
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[4] [Ru(bpy)3]2+ aided photocatalytic synthesis of 2-arylpyridines via Hantzsch reaction under visible irradiation and oxygen atmosphere
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[5] InBr3-Catalyzed Coupling Reaction between Electron-Deficient Alkenyl Ethers with Silyl Enolates for Stereoselective Synthesis of 1,5-Dioxo-alk-2-enes
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EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2021, 2021 (01) : 77 - 81

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