C-S Bond Activation of Thioesters Using Platinum(0)

被引：30
|
作者：
Kundu, Sabuj [1 ]
Brennessel, William W. [1 ]
Jones, William D. [1 ]
机构：
[1] Univ Rochester, Dept Chem, Rochester, NY 14627 USA
来源：
ORGANOMETALLICS | 2011年 / 30卷 / 19期
基金：
美国国家科学基金会;
关键词：
CARBON-SULFUR BOND; SOLUBLE METAL-COMPLEXES; OXIDATIVE ADDITION; REDUCTIVE ELIMINATION; HYDRODESULFURIZATION REACTION; (C5ME5)RH(PME3) FRAGMENT; ACTIVE-SITE; THIOPHENE; CLEAVAGE; ALKYNES;
D O I：
10.1021/om200452z
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
C-S bond activation of both cyclic and acyclic thioesters using (dippe)Pt(NBE)(2) (NBE = norbomene) are reported. In the cases of S-methyl thio acetate and S-ethyl thioacetate, (dippe)Pt(C(O)Me)(SR) (R = Me, Et) formed initially. Further heating in the presence of excess thioester led to formation of the final complex (dippe)Pt(SR)(2) along with acetone and RSMe as organic side products. Pt(IV) intermediates are proposed to be involved in the reaction mechanism.
引用
收藏
页码：5147 / 5154
页数：8
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