Carbon-silica composite adsorbent: Characterization and adsorption of light gases

被引:53
|
作者
Glover, T. Grant [1 ]
Dunne, Kamini I. [2 ]
Davis, Robert J. [2 ]
LeVan, M. Douglas [1 ]
机构
[1] Vanderbilt Univ, Dept Chem Engn, Nashville, TN 37235 USA
[2] Univ Virginia, Dept Chem Engn, Charlottesville, VA 22904 USA
关键词
adsorbent; carbon; carbon-silica composite; furfuryl alcohol; MCM-41; carbogenic molecular sieve;
D O I
10.1016/j.micromeso.2007.07.012
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
A novel carbon-silica composite has been synthesized from MCM-41 and polyfurfuryl alcohol and characterized via X-ray diffraction and nitrogen adsorption. The adsorption and X-ray diffraction studies of the parent MCM-41 and the novel material are contrasted with a carbon derived from pure polyfurfuryl alcohol. The novel material has a high surface area, 850 m(2)/g, and a narrow pore size distribution centered at approximately 5 A. The novel material is unique when compared to traditional activated carbons or templated mesoporous carbons. The pores contained in the novel material are assembled using templating techniques and are half the size of pores contained in traditional carbons. Room temperature adsorption isotherms for the novel material and MCM-41 are presented for nitrogen, carbon dioxide, methane, and ethane. (C) 2007 Elsevier Inc. All rights reserved.
引用
收藏
页码:1 / 11
页数:11
相关论文
共 50 条
  • [1] Carbon-silica composite adsorbent: Sensitivity to synthesis conditions
    Glover, T. Grant
    LeVan, M. Douglas
    MICROPOROUS AND MESOPOROUS MATERIALS, 2009, 118 (1-3) : 21 - 27
  • [2] CARBON-SILICA COMPOSITE AS ADSORBENT FOR REMOVAL OF CATIONIC DYE (METHYLENE BLUE)
    Ngernyen, Yuvarat
    Phoumixay, Channakhone
    Mountivongsa, Koungnang
    Knijnenburg, Jesper Theodorus Nicolaas
    Budsaereechai, Supattra
    SURANAREE JOURNAL OF SCIENCE AND TECHNOLOGY, 2024, 31 (04):
  • [3] A new low-cost carbon-silica composite adsorbent from a by-product of the sugar industry
    Ounphikul, Boonyisa
    Chantarasombat, Natthapat
    Hunt, Andrew J.
    Ngernyen, Yuvarat
    MATERIALS TODAY-PROCEEDINGS, 2022, 51 : 1884 - 1887
  • [4] Fabrication of silica aerogel and carbon-silica composite for dynamic adsorption of benzene from dry and wet gas streams
    Alipour, Mohammadreza
    Gupta, Vinod Kumar
    Massoudinejad, Mohamadreza
    Motahari, Siamak
    Motesaddi Zarandi, Saeed
    INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY, 2023, 103 (19) : 8091 - 8109
  • [5] Carbon-silica composite bio-sorbents with a high density of oxygen-containing sites for efficient methylene blue adsorption
    Lv, Jia-Liang
    Zhai, Shang-Ru
    Wang, Zhen-Zhen
    Lei, Zhi-Min
    An, Qing-Da
    RESEARCH ON CHEMICAL INTERMEDIATES, 2016, 42 (02) : 839 - 854
  • [6] Acid functionalized carbon-silica composite and its application for solketal production
    Nandan, Devaki
    Sreenivasulu, Peta
    Konathala, L. N. Sivakurnar
    Kumar, Manoj
    Viswanadham, Nagabhatla
    MICROPOROUS AND MESOPOROUS MATERIALS, 2013, 179 : 182 - 190
  • [7] Adsorption equilibrium, kinetics and mechanism of Pb(II) over carbon-silica composite biosorbent with designed surface oxygen groups
    Fan, Yuan
    Zhai, Shangru
    Liu, Na
    Lv, Jialiang
    Lei, Zhimin
    An, Qingda
    RESEARCH ON CHEMICAL INTERMEDIATES, 2016, 42 (02) : 869 - 891
  • [8] Carbon-Silica Xerogel and Aerogel Composites
    Liu, Chunling
    Komarneni, Sridhar
    JOURNAL OF POROUS MATERIALS, 1995, 1 (01) : 75 - 84
  • [9] Facile synthesis of nanostructured porous carbon/silica composite and its adsorption property
    Hu, Xiaoyan
    Kang, Xinru
    Chen, Tao
    Yan, Xinlong
    Zhou, Min
    Komarneni, Sridhar
    JOURNAL OF POROUS MATERIALS, 2016, 23 (03) : 833 - 836
  • [10] Adsorption characteristics of nanoporous carbon-silica composites synthesized from graphite oxide by a mechanochemical intercalation method
    Chua, Y.-H.
    Yamagishi, M.
    Wang, Z.-M.
    Kanoh, H.
    Hirotsu, T.
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2007, 312 (02) : 186 - 192