3-(4-Bromophenyl)-1-phenyl-1H-pyrazole-4-carbaldehyde

被引：5
|
作者：
Prasath, R.
Bhavana, P.
Ng, Seik Weng [1 ,2 ]
Tiekink, Edward R. T. [1 ]
机构：
[1] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia
[2] King Abdulaziz Univ, Fac Sci, Dept Chem, Jeddah, Saudi Arabia
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词：
data-to-parameter ratio = 14.3; mean σ(C-C) = 0.003 Å; R factor = 0.025; single-crystal X-ray study; T = 100 K; wR factor = 0.069;
D O I：
10.1107/S1600536811036841
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, C16H11BrN2O, the phenyl and chlorobenzene rings are twisted out of the mean plane of the pyrazole ring, forming dihedral angles of 13.70 (10) and 36.48 (10)degrees, respectively. The carbaldehyde group is also twisted out of the pyrazole plane [the C-C-C-O torsion angle is 7.9 (3)degrees]. A helical supramolecular chain along the b axis and mediated by C-H center dot center dot center dot O interactions is the most prominent feature of the crystal packing.
引用
收藏
页码：O2650 / +
页数：9
相关论文
共 50 条
  • [21] Vibrational and electronic absorption spectral studies of 5-amino-1-(4-bromophenyl)-3-phenyl-1-H-pyrazole
    Prasad, M. V. S.
    Chaitanya, Kadali
    Sri, N. Udaya
    Veeraiah, V.
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2012, 99 : 379 - 389
  • [22] Synthesis, Characterization, Molecular Docking Studies and Anticancer Activity of Schiff Bases Derived from 3-(Substituted phenyl)-1-phenyl-1H-pyrazole-4-carbaldehyde and 2-Aminophenol
    Sachin S. Wazalwar
    Anita R. Banpurkar
    Franc Perdih
    Journal of Chemical Crystallography, 2018, 48 : 185 - 199
  • [23] Ethyl 1-benzyl-3-(4-bromophenyl)-1H-pyrazole-5-carboxylate
    Jia, Jiong
    Yang, He
    Ge, Yan Qing
    Wang, Jian Wu
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O1918 - U1944
  • [24] 1-[4-(4-BROMOBENZYLIDENEAMINO)PHENYL]-3-(4-BROMOPHENYL)-2-PROPEN-1-ONE
    LI, ZD
    SU, GB
    HUANG, XY
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 1994, 50 : 1788 - 1790
  • [25] 3-Methyl-5-phenoxy-1-phenyl-1H-pyrazole-4-carbaldehyde
    Shahani, Tara
    Fun, Hoong-Kun
    Shetty, Shobhitha
    Kalluraya, Balakrishna
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O2646 - +
  • [26] 1-(4-bromophenyl)-3-(4-methylbenzoyl)thiourea
    Saeed, Aamer
    Floerke, Ulrich
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : O5036 - O5037
  • [27] 3-(4-bromophenyl)-5-(4-chlorophenyl)-1-phenyl-2-pyrazoline
    Guo, Huan-Mei
    Jian, Fang-Fang
    Xiao, Hai-Lian
    Sun, Xiao-Zheng
    Li, Yu-Feng
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : o1435 - o1436
  • [28] 3-(4-Methylphenyl)-5-[4-(methylthio)phenyl]-4,5-dihydro-1H-pyrazole-1-carbaldehyde
    Butcher, Ray J.
    Jasinski, Jerry P.
    Prasad, D. Jagadeesh
    Narayana, B.
    Yathirajan, H. S.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : O4005 - U2625
  • [29] 3-(4-bromophenyl)cyclobutanone
    Lo, Jem-Mau
    Chen, Mei-Hsun
    Cheng, Jack
    Chen, Chun-Yu
    Lu, Tian-Huey
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : O656 - O657
  • [30] 5-[(4-bromophenyl) methyleneimino]-1-[2,6-dichloro-4-(trifluoromethyl) phenyl]-1H-pyrazole-3-carbonitrile
    Li, Shu-Yan
    Zhong, Ping
    Hu, Mao-Lin
    Luo, Yi
    Li, Jin-Hai
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : O3821 - O3822
12345