Synthesis and Crystal Structure of a 1D Coordination Polymer [Cd(NITpPy)2(N(CN)2)2)]n

被引：0
|
作者：
Wang, Y. F. [1 ]
Li, S. H. [1 ]
Wang, L. Y. [1 ]
机构：
[1] Luoyang Normal Univ, Coll Chem & Chem Engn, Luoyang 471000, Henan, Peoples R China
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2011年 / 37卷 / 11期
基金：
中国国家自然科学基金;
关键词：
MAGNETIC-PROPERTIES; NITRONYL NITROXIDE; MANGANESE(II); COMPLEXES; IMINO;
D O I：
10.1134/S1070328411100137
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel one-dimensional chain complex [Cd(NITpPy)(2)(N(CN)(2))(2))](n) (NITpPy = 2-(4'-pyridyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide) has been synthesized and characterized structurally. It crystallizes in the triclinic space group P (1) over bar with a = 7.1742(13), b = 9.4913(17), c = 13.208(2) angstrom, alpha = 71.020(2)degrees, beta = 87.308(2)degrees, gamma = 70.503(2)degrees, V = 799.8(3) angstrom(3), C28H32CdN12O4, Mr = 713.06, Z = 1, rho(c) = 1.48 g/cm(3), mu(MoK alpha) = 0.736 mm(-1), F(000) = 364, R = 0.0275 and wR = 0.0605 for 2702 observed reflections with I>2 sigma(I). The crystal structure consists of infinite chains of [Cd(NITpPy)(2)(N(CN)(2))(2))] units linked by dicyanamide anions [N(CN)(2)] center dot Each Cd2+ ion is six-coordinated with the geometry of a distorted octahedron.
引用
收藏
页码：868 / 871
页数：4
相关论文
共 50 条
  • [11] Supramolecular assemblies of new 2-D complexes:: Syntheses, crystal structures, spectroscopic and magnetic properties of {[MnAu2(CN)4(NITpPy)2(H2O)2]}n and {[Co(N(CN)2)2(NITpPy)2(H2O)2]}n
    Zhou, HB
    Wang, SP
    Liu, ZQ
    Liao, DZ
    Jiang, ZH
    Yan, SP
    Cheng, P
    INORGANICA CHIMICA ACTA, 2006, 359 (02) : 533 - 540
  • [12] Synthesis, Structure and Property of a 1D Coordination Polymer [Mn{5-(NO2)sal}2(phen)]n with 5-Nitrosalicylate Ligand
    Wen De-Cai
    Xie Jing
    Jiang Xiu-Rong
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2009, 28 (03) : 279 - 282
  • [13] Synthesis, crystal structure and magnetic properties of a 1D coordination polymer[Ni(phth)(phen)(H2O)]n • nH2O
    Tian, Li
    Chen, Lin
    Shen, Shao-Hua
    Wen, Chun-Lin
    Liu, Sheng-Li
    JOURNAL OF COORDINATION CHEMISTRY, 2007, 60 (06) : 683 - 689
  • [14] Synthesis, crystal structure and optical properties of a novel 1D coordination polymer [Zn3(C7H2NO5)2•8(H2O)]n
    Zou, Jian-Ping
    Peng, Qiang
    Zeng, Gui-Sheng
    Wen, Zhen-Hai
    Xing, Qiu-Ju
    Chen, Mei-Hong
    Guo, Guo-Cong
    Huang, Jin-Shun
    JOURNAL OF MOLECULAR STRUCTURE, 2009, 921 (1-3) : 323 - 327
  • [15] A 2D Cobalt(II) Coordination Polymer [Co(iqnc)2]n: Synthesis, Crystal Structure and Characterizations
    Fan Guang
    Guo Jin-Chan
    Li Xiao-Bo
    Ma Zhan-Ying
    Deng Ling-Juan
    Zhang Yin-Li
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2015, 34 (10) : 1612 - 1616
  • [16] Synthesis, structure and dielectric constant properties of a novel 1D coordination polymer[K(2-PTA)(H2O)]n
    Fu, Da-Wei
    Ge, Jia-Zhen
    Dai, Jing
    Ye, Heng-Yun
    Qu, Zhi-Rong
    INORGANIC CHEMISTRY COMMUNICATIONS, 2009, 12 (10) : 994 - 997
  • [17] Synthesis and crystal structure of a new 1D Pb(II) coordination polymer containing salicylate and 2,2′-bipyridine ligands
    Shi, Wei-Wei
    Cheng, Yuan-Zheng
    Zhang, Li-Ping
    MAIN GROUP METAL CHEMISTRY, 2015, 38 (3-4) : 111 - 115
  • [18] Synthesis, X-ray crystal structures and magnetic properties of Cu(II)(NITpPy)2[N(CN)2]2•solv (NITpPy = nitronyl nitroxide radical, solv = H2O or CH3CN).: From discrete molecules to 2-D polymeric coordination compounds
    Dasna, I
    Golhen, S
    Ouahab, L
    Fettouhi, M
    Pena, O
    Daro, N
    Sutter, JP
    INORGANICA CHIMICA ACTA, 2001, 326 (01) : 37 - 46
  • [19] Synthesis and Crystal Structure of 1D Cd-amine Coordination Polymer and Its Luminescent Properties
    Xu Mengying
    Liu Zhigang
    Fan Ruiqing
    Gao Song
    Chen Shuo
    Yang Yulin
    CHEMICAL RESEARCH IN CHINESE UNIVERSITIES, 2014, 30 (05) : 720 - 725
  • [20] A Novel 3D Heterobimetallic Cyano-bridged Coordination Polymer {(NH4)2[Cd(H2O)Fe(CN)6]}n: Synthesis and Crystal Structure
    Qv Jing-Yan
    Mo Zong-Qiao
    Sun Ya-Qiu
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2014, 33 (07) : 990 - 994
12345