Off the Beaten TrackA Hitchhiker's Guide to Beryllium Chemistry

被引:118
作者
Naglav, Dominik [1 ]
Buchner, Magnus R. [2 ]
Bendt, Georg [1 ]
Kraus, Florian [2 ]
Schulz, Stephan [1 ]
机构
[1] Univ Duisburg Essen, Fac Chem, Univ Str 7, D-45141 Essen, Germany
[2] Univ Marburg, Anorgan Chem, Fluorchem, Hans Meerwein Str 4, D-35032 Marburg, Germany
关键词
berylliosis; beryllium; glucinium; safety; toxicology; N-HETEROCYCLIC CARBENE; LIGHT-WATER REACTORS; CD4(+) T-CELLS; STRUCTURAL-CHARACTERIZATION; 1-TRIS(PYRAZOLYL)BORATE BERYLLIUM; COORDINATION CHEMISTRY; OCCUPATIONAL-EXPOSURE; THERMAL-CONDUCTIVITY; MOLECULAR-STRUCTURE; MAGNETIC-RESONANCE;
D O I
10.1002/anie.201601809
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This Minireview aims to give an introduction to beryllium chemistry for all less-experienced scientists in this field of research. Up to date information on the toxicity of beryllium and its compounds are reviewed and several basic and necessary guidelines for a safe and proper handling in modern chemical research laboratories are presented. Interesting phenomenological observations are described that are related directly to the uniqueness of this element, which are also put into historical context. Herein we combine the contributions and experiences of many scientist that work passionately in this field. We want to encourage fellow scientists to reconcile the long-standing reservations about beryllium and its compounds and motivate intense research on this spurned element. Who on earth should be able to deal with beryllium and its compounds if not chemists?
引用
收藏
页码:10562 / 10576
页数:15
相关论文
共 129 条
[1]   THE STRUCTURE OF BERYLLIUM FILMS [J].
ADAMS, RO ;
NORDIN, CW .
THIN SOLID FILMS, 1989, 181 :375-381
[2]  
Al-Mokhtar M. H., 2010, DALTON T, V39, P4593
[3]   Using beryllium bonds to change halogen bonds from traditional to chlorine-shared to ion-pair bonds [J].
Alkorta, Ibon ;
Elguero, Jose ;
Mo, Otilia ;
Yanez, Manuel ;
Del Bene, Janet E. .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2015, 17 (03) :2259-2267
[4]   ON MOLECULAR STRUCTURE OF DI-T-BUTYL BERYLLIUM [J].
ALMENNINGEN, A ;
HAALAND, A ;
NILLSON, JE .
ACTA CHEMICA SCANDINAVICA, 1968, 22 (03) :972-+
[5]   SOME STERICALLY HINDERED BERYLLIUM ALKOXIDES AND THEIR DERIVATIVES - MONOMERIC BERYLLIUM 2,6-DI-T-BUTYLPHENOXIDE [J].
ANDERSEN, RA ;
COATES, GE .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1972, (19) :2153-&
[6]  
[Anonymous], 2009, HDB SAMPLE PREPARATI, DOI DOI 10.1007/978-0-387-85731-2
[7]  
[Anonymous], ANGEW CHEM, DOI [10.1002/ANGE.200604623, DOI 10.1002/ANGE.200604623]
[8]  
[Anonymous], 1963, Handbook of Preparative Inorganic Chemistry
[9]  
[Anonymous], 1965, PARACELSUS DRITTE DE, V2, P510
[10]  
[Anonymous], 2001, PLEASURE FINDING THI