Nickel-cobalt hydroxide catalysts for the cycloaddition of carbon dioxide to epoxides

被引:18
|
作者
Ribeiro, Stephany L. S. [1 ]
Silva, Cristiane G. [1 ]
Prado, Gabriel E. T. O. [1 ]
da Mata, Alvaro F. A. [1 ]
Milani, Jorge L. S. [2 ]
Martins, Paulo R. [1 ]
das Chagas, Rafael P. [1 ]
机构
[1] Univ Fed Goias UFG, Inst Quim, Goiania, Go, Brazil
[2] Univ Fed Juiz de Fora UFJF, Inst Ciencias Exatas, Dept Quim, Juiz De Fora, MG, Brazil
关键词
Nickel cobalt hydroxide; Carbon dioxide; CO2; fixation; Cyclic carbonate; Heterogeneous catalysis; Hydrogen bond donor; CYCLIC CARBONATES; IONIC LIQUID; PROPYLENE CARBONATE; CO2; FIXATION; EFFICIENT; CONVERSION; NI; COMPLEXES; STRATEGY; NITRIDE;
D O I
10.1007/s11164-022-04697-7
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Nickel and cobalt bimetallic hydroxides, in which both metal cations present the same oxidation state, were synthesized and characterized by XRD, TGA, TEM, XPS, and ICP-OES. The catalytic activity in the cycloaddition of carbon dioxide with epoxides was evaluated in a binary system, using tetrabutylammonium bromide as cocatalyst. All materials were active catalysts for the production of cyclic carbonates in the initial conditions, providing conversions and selectivities up to 75% and 93%, respectively. The influence of the parameters time, temperature, catalyst amount, pressure, and cocatalyst type was examined. Using the catalyst with the molar ratio 50:50 of Ni and Co (NiCo-50), a series of epoxides was converted to the respective carbonates under the optimal conditions, providing excellent conversions and selectivity. Alkylic propylene oxide and butylene oxide presented 84% and 83% of conversion, respectively. For epoxides containing electron-withdrawing substituents, the conversions were quantitative (> 99%) and highly selective to the cyclic carbonate. Reuse experiments were conducted, and showed that NiCo-50 can be recovered and reused at least five times, without decline in conversion and selectivity.
引用
收藏
页码:1907 / 1921
页数:15
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