Determination of partial molar volumes at infinite dilution of alcohols and terpenes in supercritical carbon dioxide

被引：15
|
作者：
Cortesi, A
Kikic, I
Spicka, B
Magoulas, K
Tassios, D
机构：
[1] UNIV MARIBOR,FAC TECH SCI,DEPT CHEM ENGN,MARIBOR 62000,SLOVENIA
[2] NATL TECH UNIV ATHENS,DEPT CHEM ENGN,LAB THERMODYNAM & TRANSPORT PHENOMENA,GR-15780 ATHENS,GREECE
来源：
JOURNAL OF SUPERCRITICAL FLUIDS | 1996年 / 9卷 / 03期
关键词：
partial molar volume at infinite dilution; supercritical fluid chromatography; carbon dioxide; alcohols; terpenes;
D O I：
10.1016/S0896-8446(96)90024-8
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The use of supercritical fluid chromatography for determining partial molar volumes of alcohols and terpenes at infinite dilution in supercritical CO2 is presented and discussed. Partial molar volumes at infinite dilution are obtained from the variation of the retention properties with the density of mobile phase at 313.15 K and in the pressure range from 85 to 280 bar.
引用
收藏
页码：141 / 145
页数：5
相关论文
共 50 条
  • [41] Partial Molar Volumes and Partial Molar Isentropic Compressions of Three Polyhydric Alcohols Derived from Propane at Infinite Dilution in Water at Temperatures T = (278 to 318) K and Atmospheric Pressure
    Katrinak, Tomas
    Hnedkovsky, Lubomir
    Cibulka, Ivan
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2012, 57 (04): : 1152 - 1159
  • [42] Infinite dilution partial molar excess entropy-enthalpy compensation for thiophene, carbon dioxide and water in ionic liquids
    Kato, Satoru
    Freitag, Joerg
    Gostomski, Peter
    FLUID PHASE EQUILIBRIA, 2013, 339 : 1 - 9
  • [43] Partial Molar Volumes of Selected Aliphatic Alcohols at Infinite Dilution in Water at Temperatures T = (278 to 573) K and Pressures up to 30 MPa
    Simurka, Lukag
    Cibulka, Ivan
    Hnedkovsky, Lubomir
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2011, 56 (12): : 4564 - 4576
  • [44] Molecular dynamics simulation of infinite dilution diffusivity of carbon dioxide in supercritical water
    Cai, Shengjia
    Hu, Zhan-Chao
    Li, Jiawei
    Zhang, Yan-Ling
    Zhang, Xin-Rong
    INTERNATIONAL JOURNAL OF MODERN PHYSICS B, 2018, 32 (27):
  • [45] PARTIAL MOLAR VOLUMES OF GASES DISSOLVED IN LIQUIDS .2. A DILATOMETER FOR MEASURING INFINITE-DILUTION PARTIAL MOLAR VOLUMES, AND RESULTS FOR 40 LIQUID GAS SYSTEMS
    HANDA, YP
    DARCY, PJ
    BENSON, GC
    FLUID PHASE EQUILIBRIA, 1982, 8 (02) : 181 - 196
  • [46] NONEXTRAPOLATION METHOD OF DETERMINATION OF PARTIAL MOLAR VOLUMES AND ISOENTROPIC COMPRESSION UNDER CONTINUOUS DILUTION
    ABROSIMOV, VK
    ZHURNAL FIZICHESKOI KHIMII, 1988, 62 (07): : 1913 - 1916
  • [47] Partial Molar Volumes and Partial Molar Isentropic Compressions of γ-Butyrolactone and ε-Caprolactone at Infinite Dilution in Water at Temperatures (278.15 to 318.15) K and at Atmospheric Pressure
    Bolotov, Alexander
    Cibulka, Ivan
    Hnedkovsky, Lubomir
    JOURNAL OF SOLUTION CHEMISTRY, 2011, 40 (05) : 751 - 763
  • [48] Partial Molar Volumes and Partial Molar Isentropic Compressions of γ-Butyrolactone and ε-Caprolactone at Infinite Dilution in Water at Temperatures (278.15 to 318.15) K and at Atmospheric Pressure
    Alexander Bolotov
    Ivan Cibulka
    Lubomír Hnědkovský
    Journal of Solution Chemistry, 2011, 40 : 751 - 763
  • [49] PARTIAL MOLAR QUANTITIES AT INFINITE DILUTION IN DISSOCIATING SOLVENTS
    WYATT, PAH
    JOURNAL OF THE CHEMICAL SOCIETY, 1955, : 3438 - 3441
  • [50] PARTIAL MOLAR VOLUMES AND COMPONENT VOLATILITIES OF CARBON-DIOXIDE AND HELIUM MIXTURES
    TSIKLIS, DS
    LINSHITS, LR
    RODKINA, IB
    ZHURNAL FIZICHESKOI KHIMII, 1975, 49 (05): : 1127 - 1130
12345