Determination of partial molar volumes at infinite dilution of alcohols and terpenes in supercritical carbon dioxide

被引：15

作者：

Cortesi, A

Kikic, I

Spicka, B

Magoulas, K

Tassios, D

机构：

[1] UNIV MARIBOR,FAC TECH SCI,DEPT CHEM ENGN,MARIBOR 62000,SLOVENIA

[2] NATL TECH UNIV ATHENS,DEPT CHEM ENGN,LAB THERMODYNAM & TRANSPORT PHENOMENA,GR-15780 ATHENS,GREECE

来源：

JOURNAL OF SUPERCRITICAL FLUIDS | 1996年 / 9卷 / 03期

关键词：

partial molar volume at infinite dilution; supercritical fluid chromatography; carbon dioxide; alcohols; terpenes;

D O I：

10.1016/S0896-8446(96)90024-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The use of supercritical fluid chromatography for determining partial molar volumes of alcohols and terpenes at infinite dilution in supercritical CO2 is presented and discussed. Partial molar volumes at infinite dilution are obtained from the variation of the retention properties with the density of mobile phase at 313.15 K and in the pressure range from 85 to 280 bar.

引用

页码：141 / 145

页数：5

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