Determination of partial molar volumes at infinite dilution of alcohols and terpenes in supercritical carbon dioxide

被引：15
|
作者：
Cortesi, A
Kikic, I
Spicka, B
Magoulas, K
Tassios, D
机构：
[1] UNIV MARIBOR,FAC TECH SCI,DEPT CHEM ENGN,MARIBOR 62000,SLOVENIA
[2] NATL TECH UNIV ATHENS,DEPT CHEM ENGN,LAB THERMODYNAM & TRANSPORT PHENOMENA,GR-15780 ATHENS,GREECE
来源：
JOURNAL OF SUPERCRITICAL FLUIDS | 1996年 / 9卷 / 03期
关键词：
partial molar volume at infinite dilution; supercritical fluid chromatography; carbon dioxide; alcohols; terpenes;
D O I：
10.1016/S0896-8446(96)90024-8
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The use of supercritical fluid chromatography for determining partial molar volumes of alcohols and terpenes at infinite dilution in supercritical CO2 is presented and discussed. Partial molar volumes at infinite dilution are obtained from the variation of the retention properties with the density of mobile phase at 313.15 K and in the pressure range from 85 to 280 bar.
引用
收藏
页码：141 / 145
页数：5
相关论文
共 50 条
  • [1] Infinite dilution partial molar volumes of butanal and 2-methylpropanal in supercritical carbon dioxide
    Guo, Y
    Akgerman, A
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1998, 43 (05): : 889 - 892
  • [2] The retention factors and partial molar volumes of cycloartenyl ferulate at infinite dilution in supercritical carbon dioxide: Measurements and correlation
    Fu, Yao
    Umemura, Ryohei
    Cai, Guoxiao
    Funazukuri, Toshitaka
    Tsuchiya, Yooko
    Kong, Chang Yi
    JOURNAL OF MOLECULAR LIQUIDS, 2024, 411
  • [3] Infinite dilution partial molar volumes of platinum(II) 2,4-pentanedionate in supercritical carbon dioxide
    Kong, Chang Yi
    Siratori, Tomoya
    Funazukuri, Toshitaka
    Wang, Guosheng
    JOURNAL OF CHROMATOGRAPHY A, 2014, 1362 : 294 - 300
  • [4] Binary diffusion coefficients, partition ratios and partial molar volumes at infinite dilution for β-carotene and α-tocopherol in supercritical carbon dioxide
    Funazukuri, T
    Kong, CY
    Kagei, S
    JOURNAL OF SUPERCRITICAL FLUIDS, 2003, 27 (01): : 85 - 96
  • [5] Infinite-dilution partial molar properties of azulene and acenaphthylene in supercritical carbon dioxide
    Jeon, YP
    Roth, M
    Kwon, YJ
    JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (38): : 8132 - 8136
  • [6] A STUDY ON THE MODELS FOR INFINITE DILUTION PARTIAL MOLAR VOLUMES OF SOLUTES IN SUPERCRITICAL FLUIDS
    LIU, HQ
    MACEDO, EA
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1995, 34 (06) : 2029 - 2037
  • [7] DETERMINATION OF PARTIAL MOLAR VOLUMES AT INFINITE DILUTION USING SFC TECHNIQUE
    SPICKA, B
    CORTESI, A
    FERMEGLIA, M
    KIKIC, I
    JOURNAL OF SUPERCRITICAL FLUIDS, 1994, 7 (03): : 171 - 176
  • [8] Determination of Partial Molar Volumes of EPA and DHA Ethyl Esters in Supercritical Carbon Dioxide
    Mei HUANG
    Chinese Chemical Letters, 2002, (01) : 83 - 86
  • [9] Determination of partial molar volumes of EPA and DHA ethyl esters in supercritical carbon dioxide
    Huang, M
    Wang, XD
    Xiong, RT
    Wu, PD
    Ren, QL
    CHINESE CHEMICAL LETTERS, 2002, 13 (01) : 83 - 86
  • [10] The retention factors and partial molar volumes of ibuprofen at infinite dilution in supercritical carbon dioxide at T= (308.15, 313.15, 323.15, 333.15, 343.15 and 353.15) K
    Kong, Chang Yi
    Sugiura, Kaito
    Funazukuri, Toshitaka
    Miyake, Koji
    Okajima, Izumi
    Badhulika, Sushmee
    Sako, Takeshi
    JOURNAL OF MOLECULAR LIQUIDS, 2019, 296
12345