A neo-clerodane diterpene from Teucrium tomentosum

被引：6
|
作者：
Devi, SS
Malathi, R
Rajan, SS
Aravind, S
Krishnakumari, GN
Ravikumar, K
机构：
[1] Univ Madras, Dept Crystallog & Biophys, Madras 600025, Tamil Nadu, India
[2] SPIC Sci Fdn, Madras 600032, Tamil Nadu, India
[3] Indian Inst Chem Technol, Hyderabad 500007, Andhra Pradesh, India
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2004年 / 60卷
关键词：
D O I：
10.1107/S1600536803028745
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
A neo-clerodane diterpene, 15-hydroxy-15,16-epoxy-6alpha-neocleroda-3,13(16),14-triene-18,19:20,12-diolide, C20H22O6, showing antifeedant activity against lepidopterous pests, has been isolated from Teucrium tomentosum and characterized by NMR and X-ray crystallographic methods. The crystallographic studies reveal that the cyclohexene and cyclohexane rings adopt a half-chair and a chair conformation, respectively. The furan ring exhibits rotational disorder. The molecules in the crystal structure are stabilized by a network of O-H...O and C-H...O hydrogen bonds.
引用
收藏
页码：O117 / O119
页数：3
相关论文
共 50 条
  • [21] A new neo-clerodane diterpene from Aster souliei
    Wang, LM
    Guo, SJ
    Jia, ZJ
    Cheng, DL
    CHINESE CHEMICAL LETTERS, 1996, 7 (07) : 619 - 620
  • [22] A new neo-clerodane diterpene from Ajuga decumbens
    Lv, Huawei
    Luo, Jianguang
    Kong, Lingyi
    NATURAL PRODUCT RESEARCH, 2014, 28 (03) : 196 - 200
  • [23] Ajugapyrin A, a neo-clerodane diterpene from Ajuga pyramidalis
    Boneva, IM
    Malakov, PY
    Papanov, GY
    PHYTOCHEMISTRY, 1998, 47 (02) : 303 - 305
  • [24] A NEW NEO-CLERODANE DITERPENE FROM ASTER SOULIEI
    Liang Ming WANG
    Shou Jun GUO
    Zhong Jian JIA and Dong Liang CHENG(Department of Chemistry
    Chinese Chemical Letters, 1996, (07) : 619 - 620
  • [25] HPLC analysis of neo-clerodane diterpenoids from Teucrium chamaedrys
    Avula, B
    Manyam, RB
    Bedir, E
    Khan, IA
    PHARMAZIE, 2003, 58 (07): : 494 - 496
  • [26] DIHYDROTEUGIN, A NEO-CLERODANE DITERPENOID FROM TEUCRIUM-CHAMAEDRYS
    SAVONA, G
    GARCIAALVAREZ, MC
    RODRIGUEZ, B
    PHYTOCHEMISTRY, 1982, 21 (03) : 721 - 723
  • [27] TEUMARIN, A NEO-CLERODANE DITERPENOID FROM TEUCRIUM-MARUM
    SAVONA, G
    PIOZZI, F
    SERVETTAZ, O
    FERNANDEZGADEA, F
    RODRIGUEZ, B
    PHYTOCHEMISTRY, 1984, 23 (03) : 611 - 613
  • [28] Antifeedant activity of neo-clerodane diterpenoids from Teucrium arduini
    Bruno, M
    Piozzi, F
    Maggio, AM
    Rosselli, S
    Simmonds, MSJ
    Servettaz, O
    BIOCHEMICAL SYSTEMATICS AND ECOLOGY, 2002, 30 (06) : 595 - 599
  • [29] A NEW. NEO-CLERODANE DITERPENE FROM AJUGA NIPPONENSIS
    Zhun LIU
    Chinese Chemical Letters, 1995, (07) : 581 - 582
  • [30] Amarisolide, a neo-clerodane diterpene glycoside from Salvia amarissima
    Maldonado, E
    Cardenas, J
    Bojorquez, H
    Escamilla, EM
    Ortega, A
    PHYTOCHEMISTRY, 1996, 42 (04) : 1105 - 1108
12345