Preparation of EuSe nanoparticles from Eu(III) complex containing selenides

被引:13
作者
Adachi, Taka-aki [1 ]
Tanaka, Atsushi [1 ]
Hasegawa, Yasuchika [1 ]
Kawai, Tsuyoshi [1 ]
机构
[1] Nara Inst Sci & Technol, Grad Sch Mat Sci, Ikoma, Nara 6300192, Japan
关键词
nanoparticles; lanthanide; chalcogenide;
D O I
10.1016/j.tsf.2007.04.099
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The EuSe nanoparticles were prepared by the thermal reduction of Europium nitrate with new organic selenium compound, tetraphenylphosphonium diphenylphosphinediselenide (PPh4)(Se2P(C6H5)(2)), for the first time. EuSe nanoparticles were identified by the X-ray diffraction (XRD), the transmission electron microscope (TEM) and the energy dispersive X-ray spectroscopy (EDX) measurements. The average size of the EuSe nanoparticles was found to be 19 nm. The energy gap in EuSe nanoparticles of 19 nm was estimated by edge of absorption band, giving the energy gap of 1.86 eV. (C) 2007 Elsevier B.V. All fights reserved.
引用
收藏
页码:2460 / 2462
页数:3
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