Preparation of high purity zinc from zinc oxide ore by vacuum carbothermic reduction

被引：13
|
作者：
Xiong, L. Z. [1 ,2 ,3 ]
Xiang, Y. H. [3 ]
Wu, X. W. [3 ]
He, Z. Q. [2 ,3 ]
Yin, Z. L. [1 ]
机构：
[1] Cent S Univ, Sch Chem & Chem Engn, Changsha 410083, Hunan, Peoples R China
[2] Hunan City Univ, Coll Mat & Chem Engn, Yiyang 413000, Hunan, Peoples R China
[3] Collaborat Innovat Ctr Manganese Zinc Vanadium In, Jishou 416000, Hunan, Peoples R China
来源：
VACUUM | 2017年 / 146卷
基金：
中国国家自然科学基金; 中国博士后科学基金;
关键词：
Vacuum; Carbothermic reduction; Zinc oxide ore; Zinc yield; High-purity zinc; Metallurgy; CALCIUM-CARBONATE; SULFIDE; RECOVERY; KINETICS; CATALYST;
D O I：
10.1016/j.vacuum.2017.09.050
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Effects of the yield and quality of Zn were investigated by vacuum carbothermic reduction from zinc oxide ore. Results indicate that initial moles ratio of C/Zn-Total, pressure of system, reaction time affect significantly the Zn yield from zinc oxide ore, while sintering temperature and sintering time have important influences on the quality of Zn. The optimal operating conditions are obtained as follows: the sintering temperature 973 K, the sintering time 50 min, the molar ratio of C/Zn-Total 2.5, the reaction temperature 1173 K, the pressure system lower than 20 kPa, the reaction time 50 min. Under the optimal conditions, the yield and purity of Zn are more than 95% and 99.995% respectively, suggesting the vacuum carbothermic reduction is a promising method to extract high-purity zinc from zinc oxide ore. (C) 2017 Published by Elsevier Ltd.
引用
收藏
页码：200 / 205
页数：6
相关论文
共 50 条
  • [41] Carbothermic reduction of zinc sulfide in the presence of sodium carbonate
    Chuang, Hsiang-Yu
    Lin, Chun-I
    Chen, Hsi-Kuei
    JOURNAL OF THE CHINESE INSTITUTE OF CHEMICAL ENGINEERS, 2008, 39 (05): : 457 - 465
  • [42] Carbothermic reduction of zinc sulfide in the presence of calcium carbonate
    Che-Ming Wu
    Chun-I Lin
    Hsi-Kuei Chen
    Metallurgical and Materials Transactions B, 2006, 37 : 339 - 347
  • [43] IRON OXIDE SYNERGISTIC VACUUM CARBOTHERMAL EXTRACTION OF ZINC FROM ZINC SULFIDE
    Ma, H. -Z
    Dang, Y. B.
    Wang, Y. -N
    Zeng, J. -Y
    Zhang, X.
    Guan, M. -H
    Zhao, X. -J
    JOURNAL OF MINING AND METALLURGY SECTION B-METALLURGY, 2024, 60 (02) : 259 - 269
  • [44] Preparation of Zinc Oxide and Zinc Ferrite from Zinc Hypoxide by Wet Process and Electrochemistry
    Li, Hui
    Fu, Yutian
    Liang, Jinglong
    Wang, Le
    Yan, Hongyan
    Zhao, Linfei
    CRYSTALS, 2021, 11 (09)
  • [45] Recovery of Zinc from Oxide-Sulphide Zinc Ore Through Oxidation and Chelation
    Yang, Kun
    Sun, Chengyu
    Qu, Hongtao
    Shuo, Likun
    Luo, Yongguang
    Zhang, Libo
    Ma, Aiyuan
    MATERIALS ENGINEERING-FROM IDEAS TO PRACTICE: AN EPD SYMPOSIUM IN HONOR OF JIANN-YANG HWANG, 2021, : 161 - 169
  • [46] Impacts of ultrasound on leaching recovery of zinc from low grade zinc oxide ore
    Li, Shiwei
    Chen, Weiheng
    Yin, Shaohua
    Ma, Aiyuan
    Yang, Kun
    Xie, Feng
    Zhang, Libo
    Peng, Jinhui
    GREEN PROCESSING AND SYNTHESIS, 2015, 4 (04) : 323 - 328
  • [47] ANALYSIS OF HIGH-PURITY ZINC AND ZINC ALLOYS
    不详
    NATURE, 1946, 157 (3990) : 509 - 509
  • [48] Pressure acid leaching of high silicon zinc oxide ore
    Li, Cun-Xiong
    Wei, Chang
    Fan, Gang
    Yang, Xiu-Li
    Xu, Hong-Sheng
    Deng, Zhi-Gan
    Li, Min-Ting
    Li, Xing-Bin
    Zhongguo Youse Jinshu Xuebao/Chinese Journal of Nonferrous Metals, 2009, 19 (09): : 1678 - 1683
  • [49] ETCHING OF HIGH PURITY ZINC
    BRANDT, RC
    VREELAND, T
    ADAMS, KH
    JOURNAL OF APPLIED PHYSICS, 1963, 34 (03) : 587 - &
  • [50] Study on reduction and kinetic of zinc from lead-zinc oxide
    He, Changhao
    Chen, Weiliang
    Jin, Shiyao
    Yang, Changjiang
    Li, Yun
    Min, Xiaobo
    Zeng, Pingsheng
    Zhongguo Youse Jinshu Xuebao/Chinese Journal of Nonferrous Metals, 2024, 34 (08): : 2751 - 2761
12345