Gold(I) phosphine-decorated 2,2′:6′,2"-terpyridine ligands

被引：8

作者：

Constable, Edwin C. ^{[1
]}

Housecroft, Catherine E. ^{[1
]}

Neuburger, Markus ^{[1
]}

Schaffner, Silvia ^{[1
]}

Shardlow, Ellen J. ^{[1
]}

机构：

[1] Univ Basel, Dept Chem, CH-4056 Basel, Switzerland

来源：

POLYHEDRON | 2008年 / 27卷 / 01期

关键词：

gold(I); 2,2 ': 6 ',2 ''-terpyridine; phosphine; alkyne; ligand;

D O I：

10.1016/j.poly.2007.08.034

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and characterization of the ligands R3PAu(1-H) (R =Bu-n, Ph) and (1-H)Au(mu-dppe)Au(1-H) (1 = HC CCH(2)Otpy, tpy = 2,2 ':6 ',2 ''-terpyridme) are reported. The single crystal structures of (Bu3PAu)-Bu-n(1-H) and (1-H)Au(mu-dppe)Au(1-H) have been determined, and weak hydrogen bonding rather than aurophilic interactions operate between the molecules in the solid state. (C) 2007 Elsevier Ltd. All rights reserved.

引用

页码：65 / 70

页数：6

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